170357 20260410165452.0 doi 10.1039/d6qm00041j sideral 148851 ART-2026-148851 eng Melendo, Irene Double decker NHC-cyclometallated Pt complexes for highly-efficient vacuum-deposited green OLEDs and NIR emission 2026 The dinuclear compound [{PtII(C^C*)(µ-N^N)}2] (HN^N: diphenylformamidine; HC^C* = 3-methyl-1-(naphthalen-2-yl)-1H-imidazol-2-ylidene, 3) was obtained as a pure single anti-isomer, with a Pt–Pt distance of 2.8645 Å. Under UV light, 3 reacted with haloforms to obtain the corresponding oxidized species [{PtIII(C^C*)(µ-N^N)X}2] (4-X). X-ray analysis of 4-Cl confirmed the retention of the anti-conformation and revealed a shortened Pt–Pt distance (2.6070 Å) consistent with metal–metal bonding in the Pt2(III,III) system. In addition, methylation of the electron-rich complex 3 with [Me3O]BF4 provided the mixed-valence dinuclear species [(C^C*)PtII(µ-N^N)2PtIV(C^C*)(CH3)]BF4 (5), which exhibits two distinct 195Pt NMR resonances (δ: −2373 and −3264 ppm) and a large Pt–Pt coupling constant (2155 Hz). Compound 3 shows a structureless emission band at 520 nm in 2 wt% PMMA (poly(methyl methacrylate)) film, with a photoluminescence decay of 1.80 µs and quantum yield of 0.90, typical of triplet metal–metal–to-ligand charge transfer (3MMLCT) [dσ*(Pt–Pt) → π*(C^C*)] excited states. The oxidized counterparts, 4-X, display phosphorescent emissions with maxima at 960, 970 and 1055 nm in solid state at 77 K. These are tentatively assigned to triplet axial ligand-to-metal–metal charge transfer (3XMMCT) [σ(X) → dσ*(Pt–Pt)]. Whilst complex 5 shows no emission in either the visible or near-infrared regions at 298 or 77 K. Organic light-emitting diodes (OLEDs) incorporating 3 as a green emitter demonstrate excellent device performance, achieving a turn-on voltage of 3 V, an external quantum efficiency (EQE) reaching 22% and a maximum luminance exceeding 22 000 cd m−2. Access copy available to the general public Unrestricted info:eu-repo/grantAgreement/ES/DGA/E17-23R info:eu-repo/grantAgreement/ES/MICIU/PID2024-155563NB-I00 info:eu-repo/semantics/openAccess by-nc https://creativecommons.org/licenses/by-nc/4.0/deed.es info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Weatherill, Lucy A. Martín, Antonio (orcid)0000-0002-4808-574X Pander, Piotr Dias, Fernando B. Fuertes, Sara (orcid)0000-0003-1812-3175 Sicilia, Violeta Universidad de Zaragoza (orcid)0000-0002-0257-0483 2010 760 Universidad de Zaragoza Dpto. Química Inorgánica Área Química Inorgánica (2026), [11 pp.] Mater. chem. front. Materials Chemistry Frontiers 2052-1537 2371645 http://zaguan.unizar.es/record/170357/files/texto_completo.pdf Versión publicada 2765626 http://zaguan.unizar.es/record/170357/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:170357 articulos driver 2026-04-10-13:47:12 ARTICLE