Chemical looping combustion of the aqueous phase fraction of bio-oil from biomass pyrolysis

Gracia-Monforte, César (Universidad de Zaragoza) ; Lete, Alejandro (Universidad de Zaragoza) ; Ábrego, Javier (Universidad de Zaragoza) ; Arauzo, Jesús (Universidad de Zaragoza)

Resumen: The aqueous fraction of pyrolysis bio-oil, which can account for up to 85 wt% water, is typically considered a low-value by-product due to its high water content, corrosivity, toxicity, and low heating value. Its effective utilization remains a challenge for the development of sustainable biomass valorization technologies. In this work, the potential of chemical looping combustion (CLC) was evaluated as an alternative route for converting this fraction into energy while enabling inherent CO2 capture. Several oxygen carriers (OCs) based on Cu, Fe, Ni, and Mn were screened in a fixed-bed reactor at 650 °C using a synthetic model mixture representative of the aqueous bio-oil fraction (acetone, acetic acid, phenol, p-cresol, and 2-butanone). The laboratory-synthesized CuO/Al2O3 powder OC exhibited the best performance, achieving complete oxidation of the mixture to CO2 and H2O without detectable by-products during the combustion phase. Furthermore, the selected OC demonstrated highly stable redox performance and regenerability over multiple cycles at 650 and 750 °C, with the operation at 750 °C effectively minimizing carbon deposition compared to 650 °C. Overall, this low-temperature CLC approach with a CuO/Al2O3 carrier successfully addresses prior challenges of severe carbon deposition and oxygen carrier deactivation, providing a robust pathway for aqueous bio-oil valorization.

Idioma: Inglés

DOI: 10.1016/j.jece.2026.122861

Año: 2026

Publicado en: Journal of Environmental Chemical Engineering 14, 3 (2026), 122861 [16 pp.]
ISSN: 2213-3437

Financiación: info:eu-repo/grantAgreement/ES/AEI/PID2023-1490520B-I00
Financiación: info:eu-repo/grantAgreement/ES/DGA-FEDER/T22-23R

Tipo y forma: Artículo (Versión definitiva)

Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)
Área (Departamento): Área Tecnologi. Medio Ambiente (Dpto. Ing.Quím.Tecnol.Med.Amb.)