000047859 001__ 47859
000047859 005__ 20171002111020.0
000047859 0247_ $$2doi$$a10.1016/j.colsurfa.2015.01.082
000047859 0248_ $$2sideral$$a89555
000047859 037__ $$aART-2015-89555
000047859 041__ $$aeng
000047859 100__ $$0(orcid)0000-0001-5534-0676$$aBenito, J.
000047859 245__ $$aFabrication of ultrathin films containing the metal organic framework Fe-MIL-88B-NH2 by the Langmuir-Blodgett technique
000047859 260__ $$c2015
000047859 5060_ $$aAccess copy available to the general public$$fUnrestricted
000047859 5203_ $$aIn this work, the fabrication of ultrathin films containing the metal organic framework (MOF) Fe-MIL- 88B-NH2 by the Langmuir–Blodgett (LB) technique has been explored. MOF crystals of two different sizes (1.5 ± 0.3 and 0.07 ± 0.01 µm) have been synthesized and assembled at the air–liquid interface by the LB method. The effect of the subphase pH and particle size on the film formation process has been studied. Moreover, for the first time, mixed MOF+polymer (the commercial soluble polyimide Matrimid®) LB films containing different MOF loadings have been fabricated. These experiments show that it is possible to obtain ultrathin MOF + polymer films with a controlled MOF density. Furthermore, MOF particles are homogeneously distributed in the polymer matrix, even with very large amounts of MOF (up to 95 wt%). LB films have been incorporated into materials of different nature, including glass and mica substrates and also polymeric membranes based on polysulfone Udel® and PIM-1 (polymer of intrinsic microporosity), and the modification of water contact angle after LB film deposition has been analyzed.
000047859 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/MAT2013-40566-R$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2012-33198
000047859 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-sa$$uhttp://creativecommons.org/licenses/by-nc-sa/3.0/es/
000047859 590__ $$a2.76$$b2015
000047859 591__ $$aCHEMISTRY, PHYSICAL$$b56 / 144 = 0.389$$c2015$$dQ2$$eT2
000047859 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/submittedVersion
000047859 700__ $$aFenero, M.
000047859 700__ $$0(orcid)0000-0003-1273-2690$$aSorribas, S.
000047859 700__ $$0(orcid)0000-0002-9934-1707$$aZornoza, B.
000047859 700__ $$aMsayib, K.J.
000047859 700__ $$aMcKeown, N.B.
000047859 700__ $$0(orcid)0000-0002-4954-1188$$aTéllez, C.$$uUniversidad de Zaragoza
000047859 700__ $$0(orcid)0000-0003-1512-4500$$aCoronas, J.$$uUniversidad de Zaragoza
000047859 700__ $$0(orcid)0000-0002-3492-6456$$aGascón, I.$$uUniversidad de Zaragoza
000047859 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDepartamento de Química Física$$cQuímica Física
000047859 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDepartamento de Ingeniería Química y Tecnologías del Medio Ambiente$$cIngeniería Química
000047859 773__ $$g470 (2015), 161-170$$pColloids surf., A Physicochem. eng. asp.$$tCOLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS$$x0927-7757
000047859 8564_ $$s3543424$$uhttps://zaguan.unizar.es/record/47859/files/texto_completo.pdf$$yPreprint
000047859 8564_ $$s40706$$uhttps://zaguan.unizar.es/record/47859/files/texto_completo.jpg?subformat=icon$$xicon$$yPreprint
000047859 909CO $$ooai:zaguan.unizar.es:47859$$particulos$$pdriver
000047859 951__ $$a2017-10-02-10:49:53
000047859 980__ $$aARTICLE