48364 20200811091506.0 doi 10.2174/1876214X01003010044 sideral 94079 ART-2010-94079 eng Pardey, A.J. Hydroformylation of synthetic naphtha catalyzed by a dinuclear gem-dithiolato-bridged rhodium(I) complex 2010 Access copy available to the general public Unrestricted This work focuses on the use of a gem-dithiolato-bridged rhodium(I) Rh 2(µ-S 2CBn 2)(cod) 2 complex (cod = 1,5-cyclooctadiene, Bn 2CS 2 2- = 1,3-diphenyl-2,2-dithiolatopropane) dissolved in toluene in the presence of monodentate phosphite P-donor ligand (P(OPh) 3) under carbon monoxide/hydrogen (1:1, syngas) atmosphere as an effective catalyst for hydroformylation of some olefins (oxo-reactions). The capability of this system to catalyze the hydroformylation of hex-1-ene, cyclohexene, 2,3-dimethyl-but-1-ene and 2-methyl-pent-2-ene and their quaternary mixture (synthetic naphtha) has been demonstrated. This innovative method to perform the in situ hydroformylation of the olefins present in naphthas to oxygenated products would be a promissory work for a future industrial catalytic process applicable to gasoline improving based on oxo-reactions. An important observation is that variation of CO/H 2 pressure (6.8-34.0 atm), temperature (60-80 oC), reaction time (2-10 h), rhodium concentration ((1.0-1.8)x10 -3 mol/L) affect hydroformylation reaction rates. Optimal conversion to oxygenated products were achieved under Rh = 1.8 x10 -2 mol/L, P(CO/H 2) = 34 atm (CO/H 2 = 1:1) at 80 oC for 10 h. info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2006-03973 info:eu-repo/semantics/openAccess by http://creativecommons.org/licenses/by/3.0/es/ info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Suárez, J.D. Ortega, M.C. Longo, C. (orcid)0000-0002-3327-0918 Pérez-Torrente, J.J. Universidad de Zaragoza (orcid)0000-0001-7154-7239 Oro, L.A. Universidad de Zaragoza 2010 760 Universidad de Zaragoza Dpto. Química Inorgánica Área Química Inorgánica 3, 1 (2010), 44-49 Open catal. j. Open catalysis journal 1876-214X 685177 http://zaguan.unizar.es/record/48364/files/texto_completo.pdf Versión publicada 116334 http://zaguan.unizar.es/record/48364/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:48364 articulos driver 2020-08-11-09:02:30 ARTICLE