48706 20200221144248.0 doi 10.3762/bjoc.12.50 sideral 94753 ART-2016-94753 eng (orcid)0000-0001-9988-0287 Giménez Sonsona, I. The aminoindanol core as a key scaffold in bifunctional organocatalysts 2016 Access copy available to the general public Unrestricted The 1,2-aminoindanol scaffold has been found to be very efficient, enhancing the enantioselectivity when present in organocatalysts. This may be explained by its ability to induce a bifunctional activation of the substrates involved in the reaction. Thus, it is easy to find hydrogen-bonding organocatalysts ((thio)ureas, squaramides, quinolinium thioamide, etc.) in the literature containing this favored structural core. They have been successfully employed in reactions such as Friedel-Crafts alkylation, Michael addition, Diels-Alder and aza-Henry reactions. However, the 1,2-aminoindanol core incorporated into proline derivatives has been scarcely explored. Herein, the most representative and illustrative examples are compiled and this review will be mainly focused on the cases where the aminoindanol moiety confers bifunctionality to the organocatalysts. info:eu-repo/grantAgreement/ES/DGA/E104 info:eu-repo/grantAgreement/ES/MICINN/CTQ2013-44367-C2-1-P info:eu-repo/grantAgreement/ES/UZ/JIUZ-2014-CIE-07 info:eu-repo/semantics/openAccess by http://creativecommons.org/licenses/by/3.0/es/ 2.337 2016 CHEMISTRY, ORGANIC 25 / 59 = 0.424 2016 Q2 T2 1.02 2016 Organic Chemistry 2016 Q1 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion (orcid)0000-0001-6832-8983 Marqués-López, E. Universidad de Zaragoza (orcid)0000-0002-5244-9569 Herrera, R.P. Universidad de Zaragoza 2013 765 Universidad de Zaragoza Dpto. Química Orgánica Área Química Orgánica 12 (2016), 505-523 Beilstein J. Org. Chem. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY 1860-5397 1279373 http://zaguan.unizar.es/record/48706/files/texto_completo.pdf Versión publicada 75179 http://zaguan.unizar.es/record/48706/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:48706 articulos driver 2020-02-21-13:26:39 ARTICLE