Theoretical design of tetra(arenediyl)bis(allyl) derivatives as model compounds for Cope rearrangement transition states
Resumen: Several systems formed by two allyl fragments linked by four arenediyl tethers have been studied through DFT calculations. A delocalised bis(allyl) system, similar to Cope rearrangement transition states, is preferred for derivatives bearing 5-membered ring tethers, as a result of the large strain in the related localised geometry
Idioma: Inglés
DOI: 10.1039/c4ra16381h
Año: 2015
Publicado en: RSC ADVANCES 5, 15 (2015), 11494-11497
ISSN: 2046-2069

Factor impacto JCR: 3.289 (2015)
Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 48 / 162 = 0.296 (2015) - Q2 - T1
Factor impacto SCIMAGO:

Financiación: info:eu-repo/grantAgreement/ES/DGA/E11
Financiación: info:eu-repo/grantAgreement/ES/MINECO/CTQ2011-28124
Tipo y forma: Article (Published version)
Área (Departamento): Química Orgánica (Departamento de Química Orgánica)

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