000056359 001__ 56359
000056359 005__ 20210121114512.0
000056359 0247_ $$2doi$$a10.1007/s10494-015-9635-z
000056359 0248_ $$2sideral$$a92221
000056359 037__ $$aART-2015-92221
000056359 041__ $$aeng
000056359 100__ $$0(orcid)0000-0002-4674-3614$$aAlexandrino, K.$$uUniversidad de Zaragoza
000056359 245__ $$a2-methylfuran Oxidation in the Absence and Presence of NO
000056359 260__ $$c2015
000056359 5060_ $$aAccess copy available to the general public$$fUnrestricted
000056359 5203_ $$a2-methylfuran (2-MF) has become of interest as biofuel because of its properties and the improvement in its production method, and also because it is an important intermediate in the conversion of 2, 5-dimethylfuran. In this research, an experimental and kinetic modelling study of the oxidation of 2-MF in the absence and presence of NO has been performed in an atmospheric pressure laboratory installation. The experiments were performed in a flow reactor and covered the temperature range from 800 to 1400 K, for mixtures from very fuel-rich to very fuel-lean, highly diluted in nitrogen. The inlet 2-MF concentration was 100 ppm. In the experiments in the presence of NO, the inlet NO concentration was 900 ppm. An interpretation of the experimental results was performed through a gas-phase chemical kinetic model. A reasonable agreement between the experimental trends and the modelling data is obtained. The results of the concentration profile of 2-MF as a function of temperature indicate that, both in the absence and in the presence of NO, the onset of 2-MF consumption is shifted to lower temperatures only under fuel-lean and very fuel-lean conditions. Furthermore, under these conditions the presence of NO also shifts the onset of 2-MF consumption to lower temperatures. The effect of the 2-MF presence on the NO reduction varies with the oxygen concentration. It is seen that under very fuel-rich and stoichiometric conditions NO is reduced basically by reburn reactions, while under fuel-lean and very fuel-lean conditions, the NO-NO2 interconversion appears to be dominant.
000056359 536__ $$9info:eu-repo/grantAgreement/ES/DGA/GPT$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2012-34423
000056359 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000056359 590__ $$a1.863$$b2015
000056359 591__ $$aTHERMODYNAMICS$$b18 / 58 = 0.31$$c2015$$dQ2$$eT1
000056359 591__ $$aMECHANICS$$b40 / 135 = 0.296$$c2015$$dQ2$$eT1
000056359 592__ $$a1.084$$b2015
000056359 593__ $$aChemical Engineering (miscellaneous)$$c2015$$dQ1
000056359 593__ $$aPhysics and Astronomy (miscellaneous)$$c2015$$dQ1
000056359 593__ $$aPhysical and Theoretical Chemistry$$c2015$$dQ1
000056359 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000056359 700__ $$0(orcid)0000-0001-5426-6486$$aMillera, Á.$$uUniversidad de Zaragoza
000056359 700__ $$0(orcid)0000-0002-5420-0943$$aBilbao, R.$$uUniversidad de Zaragoza
000056359 700__ $$0(orcid)0000-0003-4679-5761$$aAlzueta, M.U.$$uUniversidad de Zaragoza
000056359 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000056359 7102_ $$15005$$2790$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Tecnologi. Medio Ambiente
000056359 773__ $$g(2015), [20 pp.]$$pFlow turbul. combust.$$tFlow, Turbulence and Combustion$$x1386-6184
000056359 8564_ $$s2336458$$uhttps://zaguan.unizar.es/record/56359/files/texto_completo.pdf$$yPostprint
000056359 8564_ $$s54275$$uhttps://zaguan.unizar.es/record/56359/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000056359 909CO $$ooai:zaguan.unizar.es:56359$$particulos$$pdriver
000056359 951__ $$a2021-01-21-10:58:03
000056359 980__ $$aARTICLE