Efficient and facile tuning of Vulcan XC72 with ultra-small Pt nanoparticles for electrocatalytic applications
Financiación FP7 / Fp7 Funds
Resumen: In this work, we report the synergic combination of tiny, reproducible, and crystalline platinum nanoparticles with functionalized Vulcan XC72 support for the preparation of efficient electrocatalysts. The morphology and crystallinity of Pt NPs, the amination of carbon support and the Pt loading have been properly evaluated by TEM, STEM, ATR-FTIR, XPS and microwave plasma-atomic emission spectrometry MP-AES. The electrochemical performance of the as prepared powders has been evaluated and compared with the exhibited by commercial Pt-ETEK catalyst with similar Pt-loadings, i.e. 20% wt. The herein described electrocatalyst shows higher dispersion (98.2 m2 gPt-1) of Pt nanoparticles (1.5 ± 0.3 nm in size) and strong metal–support interaction than commercial Pt-ETEK counterpart, highlighting the elevated mass activity for methanol electrooxidation.
Idioma: Inglés
DOI: 10.1039/C5RA16698E
Año: 2015
Publicado en: RSC Advances 5 (2015), 90691–90697
ISSN: 2046-2069

Factor impacto JCR: 3.289 (2015)
Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 48 / 163 = 0.294 (2015) - Q2 - T1
Factor impacto SCIMAGO:

Financiación: info:eu-repo/grantAgreement/EC/FP7/209481/EU/NANOSTRUCTURED ELECTROLYTE MEMBRANES BASED ON POLYMER-IONIC LIQUIDS-ZEOLITE COMPOSITES FOR HIGH TEMPERATURE PEM FUEL CELL/ZEOCELL
Financiación: info:eu-repo/grantAgreement/ES/MICINN/MAT2011-24988
Tipo y forma: Article (PostPrint)

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