000057733 001__ 57733
000057733 005__ 20210121114509.0
000057733 0247_ $$2doi$$a10.1039/c4nj02071e
000057733 0248_ $$2sideral$$a89623
000057733 037__ $$aART-2015-89623
000057733 041__ $$aeng
000057733 100__ $$aFedeli, E.
000057733 245__ $$aSelf-assembling amphiphilic Janus dendrimers: Mesomorphic properties and aggregation in water
000057733 260__ $$c2015
000057733 5060_ $$aAccess copy available to the general public$$fUnrestricted
000057733 5203_ $$aThe self-assembly behaviour both in bulk and in water of amphiphilic dendrimeric derivatives based on bis-MPA is the central theme of this article. The designed molecules possess two parts with different polarity// this feature is the key factor that forces their self-assembly in water into supramolecular architectures, due to hydrophobic interactions between the lipophilic fractions of the molecules, and the appearance of mesomorphic order in bulk in response to a variation of temperature (thermotropic liquid crystals). The effects provoked by the hydrophilic/lipophilic balance of the molecule were studied varying the generation of the corresponding dendrons and combining them via CuAAC click chemistry in order to obtain symmetrical and unsymmetrical final Janus dendrimers. The ability of the aggregates formed in water to encapsulate hydrophobic drugs has also been explored.
000057733 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/MAT2012-38538-C03-01$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2012-35692$$9info:eu-repo/grantAgreement/EC/FP7/215884/EU/Functional liquid Crystalline dendrimers: Synthesis of New Materials, Resource for New Applications/DENDREAMERS$$9info:eu-repo/grantAgreement/ES/DGA/E04
000057733 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/
000057733 590__ $$a3.277$$b2015
000057733 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b49 / 163 = 0.301$$c2015$$dQ2$$eT1
000057733 592__ $$a0.935$$b2015
000057733 593__ $$aChemistry (miscellaneous)$$c2015$$dQ1
000057733 593__ $$aMaterials Chemistry$$c2015$$dQ1
000057733 593__ $$aCatalysis$$c2015$$dQ2
000057733 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000057733 700__ $$0(orcid)0000-0001-6584-6603$$aLancelot, A.$$uUniversidad de Zaragoza
000057733 700__ $$0(orcid)0000-0001-9866-6633$$aSerrano, J.L.$$uUniversidad de Zaragoza
000057733 700__ $$aCalvo, P.
000057733 700__ $$0(orcid)0000-0001-7091-077X$$aSierra, T.$$uUniversidad de Zaragoza
000057733 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000057733 773__ $$g39, 3 (2015), 1960-1967$$pNew j. chem.$$tNEW JOURNAL OF CHEMISTRY$$x1144-0546
000057733 8564_ $$s764516$$uhttps://zaguan.unizar.es/record/57733/files/texto_completo.pdf$$yPostprint
000057733 8564_ $$s118168$$uhttps://zaguan.unizar.es/record/57733/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000057733 909CO $$ooai:zaguan.unizar.es:57733$$particulos$$pdriver
000057733 951__ $$a2021-01-21-10:55:42
000057733 980__ $$aARTICLE