000057743 001__ 57743
000057743 005__ 20200221144123.0
000057743 0247_ $$2doi$$a10.1016/j.renene.2015.11.025
000057743 0248_ $$2sideral$$a92415
000057743 037__ $$aART-2016-92415
000057743 041__ $$aeng
000057743 100__ $$0(orcid)0000-0003-0297-3503$$aIglesia Pedraza, Oscar de la
000057743 245__ $$aMetal-organic framework MIL-101(Cr) based mixed matrix membranes for esterification of ethanol and acetic acid in a membrane reactor
000057743 260__ $$c2016
000057743 5060_ $$aAccess copy available to the general public$$fUnrestricted
000057743 5203_ $$aMixed matrix membranes (MMMs) based on the polyimide Matrimid® (PI) with metal-organic framework (MOF) MIL-101(Cr) as porous nanostructured filler were synthesized and applied as separation element in a membrane reactor to carry out the esterification of acetic acid with ethanol. The MMMs were characterized by techniques including X-ray diffraction, IR spectroscopy and scanning electron microscopy. In order to compare the performance of MIL-101(Cr)-PI MMMs in the membrane reactor, pure PI and HKUST-1-PI membranes were also used. MMMs provided a better reactor performance than
the bare PI membrane because of the increase in permeability associated to the presence of MOF as filler. The PI membrane reactor barely achieved the same conversion as a fixed bed reactor, while the MIL- 101(Cr)-PI membrane showed a reactor performance similar to that of the HKUST-1-PI membrane with higher stability, as confirmed by membrane characterization after the reaction experiments.
000057743 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/MAT2013-40566-R
000057743 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000057743 590__ $$a4.357$$b2016
000057743 591__ $$aGREEN & SUSTAINABLE SCIENCE & TECHNOLOGY$$b7 / 31 = 0.226$$c2016$$dQ1$$eT1
000057743 591__ $$aENERGY & FUELS$$b18 / 92 = 0.196$$c2016$$dQ1$$eT1
000057743 592__ $$a1.661$$b2016
000057743 593__ $$aRenewable Energy, Sustainability and the Environment$$c2016$$dQ1
000057743 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/submittedVersion
000057743 700__ $$0(orcid)0000-0003-1273-2690$$aSorribas, Sara
000057743 700__ $$aAlmendro, Eduardo
000057743 700__ $$0(orcid)0000-0002-9934-1707$$aZornoza, Beatriz
000057743 700__ $$0(orcid)0000-0002-4954-1188$$aTéllez, Carlos$$uUniversidad de Zaragoza
000057743 700__ $$0(orcid)0000-0003-1512-4500$$aCoronas, Joaquín$$uUniversidad de Zaragoza
000057743 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000057743 773__ $$g88 (2016), 12-19$$pRenew. energy$$tRENEWABLE ENERGY$$x0960-1481
000057743 8564_ $$s5426301$$uhttps://zaguan.unizar.es/record/57743/files/texto_completo.pdf$$yPreprint
000057743 8564_ $$s70270$$uhttps://zaguan.unizar.es/record/57743/files/texto_completo.jpg?subformat=icon$$xicon$$yPreprint
000057743 909CO $$ooai:zaguan.unizar.es:57743$$particulos$$pdriver
000057743 951__ $$a2020-02-21-13:03:01
000057743 980__ $$aARTICLE