57746 20200221144207.0 doi 10.1021/acsami.6b04272 sideral 95580 ART-2016-95580 eng (orcid)0000-0001-5534-0676 Benito. J Langmuir-Blodgett Films of the Metal-Organic Framework MIL-101(Cr): Preparation, Characterization, and CO2 Adsorption Study Using a QCM-Based Setup 2016 Access copy available to the general public Unrestricted This work reports the fabrication and characterization of Langmuir–Blodgett films of nanoparticles (size 51 ± 10 nm) of the metal organic framework MIL-101(Cr). LB film characterization by SEM, UV–vis, GIXRD, and QCM has shown that the addition of 1 wt % of behenic acid to MOF dispersion allows obtaining dense monolayers at the air–water interface that can be deposited onto solid substrates of different nature with transfer ratios close to 1. Moreover, a QCM-based setup has been built and used for the first time to measure CO2 adsorption isotherms at 303 K on MOF LB films, proving that LB films with MOF masses between 1.2 (1 layer) and 2.3 (2 layers) µg can be used to obtain accurate adsorption values at 100 kPa, similar to those obtained by conventional adsorption methods that require much larger MOF quantities (tens of milligrams). info:eu-repo/grantAgreement/ES/UZ/JIUZ-2015-CIE-02 info:eu-repo/grantAgreement/EC/FP7/608490/EU/Energy efficient MOF-based Mixed Matrix Membranes for CO2 Capture/M4CO2 info:eu-repo/grantAgreement/ES/DGA/T05 info:eu-repo/grantAgreement/ES/DGA/E54 info:eu-repo/semantics/openAccess by http://creativecommons.org/licenses/by/3.0/es/ 7.504 2016 NANOSCIENCE & NANOTECHNOLOGY 12 / 87 = 0.138 2016 Q1 T1 MATERIALS SCIENCE, MULTIDISCIPLINARY 22 / 275 = 0.08 2016 Q1 T1 2.56 2016 Materials Science (miscellaneous) 2016 Q1 Nanoscience and Nanotechnology 2016 Q1 Medicine (miscellaneous) 2016 Q1 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion (orcid)0000-0003-1273-2690 Sorribas. S (orcid)0000-0003-0271-8713 Lucas. I Universidad de Zaragoza (orcid)0000-0003-1512-4500 Coronas. J Universidad de Zaragoza (orcid)0000-0002-3492-6456 Gascon.I Universidad de Zaragoza 5005 555 Universidad de Zaragoza Dpto. Ing.Quím.Tecnol.Med.Amb. Área Ingeniería Química 2012 755 Universidad de Zaragoza Dpto. Química Física Área Química Física 2003 395 Universidad de Zaragoza Dpto. Física Materia Condensa. Área Física Materia Condensada 8, 25 (2016), 16486-16492 ACS appl. mater. interfaces ACS Applied Materials & Interfaces 1944-8244 4084297 http://zaguan.unizar.es/record/57746/files/texto_completo.pdf Postprint 42290 http://zaguan.unizar.es/record/57746/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:57746 articulos driver 2020-02-21-13:10:23 ARTICLE