000057930 001__ 57930
000057930 005__ 20200221144225.0
000057930 0247_ $$2doi$$a10.1039/c6cc00267f
000057930 0248_ $$2sideral$$a97178
000057930 037__ $$aART-2016-97178
000057930 041__ $$aeng
000057930 100__ $$aValencia Calvo, Marta
000057930 245__ $$aEnhanced product selectivity promoted by remote metal coordination in acceptor-free alcohol dehydrogenation catalysis
000057930 260__ $$c2016
000057930 5060_ $$aAccess copy available to the general public$$fUnrestricted
000057930 5203_ $$aA bimetallic [Ir3+]2 complex was synthesized based on a bridging 1,2,3-triazole ligand that coordinates to one Cp*Ir unit as N,N-bidentate chelate, and to the other as a C,C-bidentate ligand. When compared to monometallic homologues, the bimetallic complex shows greatly enhanced product selectivity for the acceptorless dehydrogenation of alcohols; spectroscopic and electrochemical analysis suggest significant alteration of the metal properties in the bimetallic system compared to the monometallic species, which offers a rationale for the observed high selectivity.
000057930 536__ $$9info:eu-repo/grantAgreement/EC/H2020/660929/EU/CoopClickCat/CoopClickCat$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 660929-CoopClickCat$$9info:eu-repo/grantAgreement/EC/H2020/660929/EU/CoopClickCat/CoopClickCat$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 660929-CoopClickCat
000057930 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000057930 590__ $$a6.319$$b2016
000057930 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b23 / 166 = 0.139$$c2016$$dQ1$$eT1
000057930 592__ $$a2.537$$b2016
000057930 593__ $$aCatalysis$$c2016$$dQ1
000057930 593__ $$aCeramics and Composites$$c2016$$dQ1
000057930 593__ $$aChemistry (miscellaneous)$$c2016$$dQ1
000057930 593__ $$aSurfaces, Coatings and Films$$c2016$$dQ1
000057930 593__ $$aMaterials Chemistry$$c2016$$dQ1
000057930 593__ $$aMetals and Alloys$$c2016$$dQ1
000057930 593__ $$aElectronic, Optical and Magnetic Materials$$c2016$$dQ1
000057930 655_4 $$ainfo:eu-repo/semantics/conferenceObject$$vinfo:eu-repo/semantics/publishedVersion
000057930 700__ $$aMüller-Binz, Helge
000057930 700__ $$aGossage, Robert A.
000057930 700__ $$aAlbrecht, Martin
000057930 773__ $$g52 (2016), 3344-3347$$pChem. commun.$$tCHEMICAL COMMUNICATIONS$$x1359-7345
000057930 8564_ $$s1799333$$uhttps://zaguan.unizar.es/record/57930/files/texto_completo.pdf$$yVersión publicada
000057930 8564_ $$s111868$$uhttps://zaguan.unizar.es/record/57930/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000057930 909CO $$ooai:zaguan.unizar.es:57930$$particulos$$pdriver
000057930 951__ $$a2020-02-21-13:17:22
000057930 980__ $$aARTICLE