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<dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:invenio="http://invenio-software.org/elements/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd"><dc:identifier>doi:10.1016/j.jcat.2015.11.016</dc:identifier><dc:language>eng</dc:language><dc:creator>Murillo, B.</dc:creator><dc:creator>Zornoza, B.</dc:creator><dc:creator>De La Iglesia, O.</dc:creator><dc:creator>Téllez, C.</dc:creator><dc:creator>Coronas, J.</dc:creator><dc:title>Chemocatalysis of sugars to produce lactic acid derivatives on zeolitic imidazolate frameworks</dc:title><dc:identifier>ART-2016-93220</dc:identifier><dc:description>Several research studies related to biorefining have focused on developing routes for biomass conversion into biomaterials or platform molecules. In this work, the zeolitic imidazolate frameworks (ZIFs) ZIF-8 and ZIF-67 have been tested as catalysts in the conversion of sugars (sucrose, glucose and fructose) into methyl lactate. ZIF-8 and ZIF-67 have the same sodalite type zeolite structure but behaved differently in the sugar conversion in methanol due to the respective presence of Zn and Co in their structures. ZIF-8 has been found to be the most active for the conversion of sugars into methyl lactate (yield 42%) and was reused in four catalytic cycles. The chemical and physical effects caused by these cycles on the catalysts have been studied by several techniques (X-ray diffraction, thermogravimetric analyses, infrared spectroscopy, X-ray photoelectron spectroscopy, scanning electronic microscopy and nitrogen adsorption).</dc:description><dc:date>2016</dc:date><dc:source>http://zaguan.unizar.es/record/60603</dc:source><dc:doi>10.1016/j.jcat.2015.11.016</dc:doi><dc:identifier>http://zaguan.unizar.es/record/60603</dc:identifier><dc:identifier>oai:zaguan.unizar.es:60603</dc:identifier><dc:relation>info:eu-repo/grantAgreement/ES/MINECO/MAT2013-40566-R</dc:relation><dc:relation>info:eu-repo/grantAgreement/ES/DGA/T05</dc:relation><dc:identifier.citation>Journal of Catalysis 334 (2016), 60-67</dc:identifier.citation><dc:rights>by-nc-nd</dc:rights><dc:rights>http://creativecommons.org/licenses/by-nc-nd/3.0/es/</dc:rights><dc:rights>info:eu-repo/semantics/openAccess</dc:rights></dc:dc>

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