000060605 001__ 60605
000060605 005__ 20200221144310.0
000060605 0247_ $$2doi$$a10.1039/c5ra23134e
000060605 0248_ $$2sideral$$a94317
000060605 037__ $$aART-2016-94317
000060605 041__ $$aeng
000060605 100__ $$0(orcid)0000-0002-0157-9507$$aPerea-Cachero, C.$$uUniversidad de Zaragoza
000060605 245__ $$aSynthesis, structure and characterization of a layered coordination polymer based on Zn(II) and 6-(methylmercapto)purine
000060605 260__ $$c2016
000060605 5060_ $$aAccess copy available to the general public$$fUnrestricted
000060605 5203_ $$aA layered coordination polymer (LCP) named UZAR-S12 was synthesized. Its structure and formula [Zn2(µ2-mMP)3(NO3)(DMF)(H2O)]n·nDMF (mMP, 6-(methylmercapto)purinate; DMF, N,N-dimethylformamide) were determined by single crystal X-ray diffraction. UZAR-S12 is characterized by two kinds of Zn centres. Zn1 is bonded to three mMP ligands at the basal plane, and one water molecule and one DMF molecule at the axial positions, giving rise to a slightly distorted trigonal bipyramidal geometry. Zn2 is coordinated to three mMP linkers and one NO3- resulting in a tetrahedral environment. The layers are arranged yielding a three-dimensional network with guest DMF trapped between them. Lattice and coordination DMF can be replaced reversibly by other solvents producing a contraction (methanol) or an expansion (N,N-diethylformamide) of the framework. A solvent exchange method was used from the vapour phase which preserved the sample crystallinity.
000060605 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/MAT2013-40566-R$$9info:eu-repo/grantAgreement/ES/DGA/T05
000060605 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/
000060605 590__ $$a3.108$$b2016
000060605 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b59 / 166 = 0.355$$c2016$$dQ2$$eT2
000060605 592__ $$a0.889$$b2016
000060605 593__ $$aChemistry (miscellaneous)$$c2016$$dQ1
000060605 593__ $$aChemical Engineering (miscellaneous)$$c2016$$dQ1
000060605 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000060605 700__ $$0(orcid)0000-0002-5967-2827$$aSeoane, B.
000060605 700__ $$0(orcid)0000-0002-9512-3913$$aDiosdado, B.$$uUniversidad de Zaragoza
000060605 700__ $$0(orcid)0000-0002-4954-1188$$aTéllez, C.$$uUniversidad de Zaragoza
000060605 700__ $$0(orcid)0000-0003-1512-4500$$aCoronas, J.$$uUniversidad de Zaragoza
000060605 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000060605 7102_ $$10$$2X$$aUniversidad de Zaragoza$$bServ.Gral. Apoyo Investigación$$cServicios. Div.Caract.Físi.Quí
000060605 773__ $$g6, 1 (2016), 260-268$$pRSC ADVANCES$$tRSC Advances$$x2046-2069
000060605 8564_ $$s2056826$$uhttps://zaguan.unizar.es/record/60605/files/texto_completo.pdf$$yVersión publicada
000060605 8564_ $$s114508$$uhttps://zaguan.unizar.es/record/60605/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000060605 909CO $$ooai:zaguan.unizar.es:60605$$particulos$$pdriver
000060605 951__ $$a2020-02-21-13:36:43
000060605 980__ $$aARTICLE