000060611 001__ 60611
000060611 005__ 20190709135453.0
000060611 0247_ $$2doi$$a10.1021/acs.cgd.6b01776
000060611 0248_ $$2sideral$$a97970
000060611 037__ $$aART-2017-97970
000060611 041__ $$aeng
000060611 100__ $$aGuesh, K.
000060611 245__ $$aSustainable preparation of MIL-100(Fe) and its photocatalytic behavior in the degradation of methyl orange in water
000060611 260__ $$c2017
000060611 5060_ $$aAccess copy available to the general public$$fUnrestricted
000060611 5203_ $$aThe real industrial establishment of MOFs requires significant advances in economic and chemical sustainability. This work describes a novel and simple method to prepare one of the most widely studied MOF material, i.e. MIL-100(Fe), which significantly improves the sustainability of the conventional process in several aspects. Interestingly, the only difference in the preparation method of MIL-100(Fe) compared with that of semi-amorphous Fe-BTC (MOF material commercialized as Basolite F300 having the same metal and linker, and which can be also prepared under similar sustainable conditions), is to start from Fe(II) or Fe(III) sources, respectively, which opens certain versatility options in the room temperature synthesis procedures of MOF materials. The prepared samples were characterized using XRD, TGA, N2 adsorption/ desorption isotherms, Cs-aberration corrected STEM and UV-Vis DRS. These two room-temperature-made Fe-BTC materials were tested in the industrially-demanded photocatalytic degradation of methyl orange under both ultraviolet and solar light radiation. MIL-100(Fe) was a very active photocatalyst in comparison with its homologue. That difference was mainly attributed to the presence of larger cavities within its structure.
000060611 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/MAT2016-77496-R$$9info:eu-repo/grantAgreement/EC/FP7/312483/EU/Enabling Science and Technology through European Electron Microscopy/ESTEEM 2
000060611 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000060611 590__ $$a3.972$$b2017
000060611 591__ $$aCRYSTALLOGRAPHY$$b6 / 26 = 0.231$$c2017$$dQ1$$eT1
000060611 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b60 / 285 = 0.211$$c2017$$dQ1$$eT1
000060611 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b46 / 171 = 0.269$$c2017$$dQ2$$eT1
000060611 592__ $$a1.154$$b2017
000060611 593__ $$aChemistry (miscellaneous)$$c2017$$dQ1
000060611 593__ $$aMaterials Science (miscellaneous)$$c2017$$dQ1
000060611 593__ $$aCondensed Matter Physics$$c2017$$dQ1
000060611 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000060611 700__ $$aCaiuby, C. A. D.
000060611 700__ $$0(orcid)0000-0002-5229-2717$$aMayoral, A.
000060611 700__ $$aDiaz-Garcia, M.
000060611 700__ $$aDiaz, I.
000060611 700__ $$aSanchez-Sanchez, M.
000060611 773__ $$g17 (2017), 1806–1813$$pCryst. growth des.$$tCRYSTAL GROWTH & DESIGN$$x1528-7483
000060611 8564_ $$s1776840$$uhttps://zaguan.unizar.es/record/60611/files/texto_completo.pdf$$yPostprint
000060611 8564_ $$s73212$$uhttps://zaguan.unizar.es/record/60611/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000060611 909CO $$ooai:zaguan.unizar.es:60611$$particulos$$pdriver
000060611 951__ $$a2019-07-09-11:42:18
000060611 980__ $$aARTICLE