60650 20171221090011.0 doi 10.3390/inorganics2030508 sideral 98059 ART-2014-98059 eng (orcid)0000-0002-0257-0483 Sicilia, Violeta Universidad de Zaragoza Half-Lantern Pt(II) and Pt(III) Complexes. New Cyclometalated Platinum Derivatives 2014 Access copy available to the general public Unrestricted The divalent complex {Pt(bzq)(µ-L)}2] (1) Hbzq = benzoh]quinolone, HL = CF3C4H2N2SH: 4-(trifluoromethyl)pyrimidine-2-thiol] was obtained from equimolar amounts of Pt(bzq)(NCMe)2]ClO4 and 4-(trifluoromethyl)pyrimidine-2-thiol with an excess of NEt3. The presence of a low intensity absorption band at 486 nm (CH2Cl2), assignable to a metal-metal-to-ligand charge transfer transition (1MMLCT) ds*(Pt)2¿p*(bzq)], is indicative of the existence of two platinum centers located in close proximity because the rigidity of the half-lantern structure allows the preservation of these interactions in solution. Compound 1 undergoes two-electron oxidation upon treatment with halogens X2 (X2: Cl2, Br2 or I2) to give the corresponding dihalodiplatinum (III) complexes {Pt(bzq)(µ-L)X}2] (L = CF3C4H2N2S-¿N, S; X: Cl 2, Br 3, I 4). Complexes 2–4 were also obtained by reaction of 1 with HX (molar ratio 1:2, 10% excess of HX) in THF with yields of about 80% and compound 2 was also obtained by reaction of {Pt(bzq)(µ-Cl)}2] with HL (4-(trifluoromethyl)pyrimidine-2-thiol) in molar ratio 1:2 in THF, although in small yield. The X-ray structures of 2 and 3 confirmed the half-lantern structure and the anti configuration of the molecules. Both of them show Pt–Pt distances (2.61188(15) Å 2, 2.61767(16) Å 3) in the low range of those observed in Pt2(III, III)X2 half-lantern complexes. info:eu-repo/grantAgreement/ES/DGA/E21 info:eu-repo/grantAgreement/ES/MICINN/CTQ2008-06669-C02 info:eu-repo/grantAgreement/ES/MINECO/CTQ2012-35251 info:eu-repo/semantics/openAccess by http://creativecommons.org/licenses/by/3.0/es/ info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion (orcid)0000-0001-9003-1051 Borja, Pilar Universidad de Zaragoza (orcid)0000-0002-4808-574X Martín, Antonio Universidad de Zaragoza 2010 760 Universidad de Zaragoza Departamento de Química Inorgánica Química Inorgánica 2, 3 (2014), 508-523 Inorganics 2304-6740 1122812 http://zaguan.unizar.es/record/60650/files/texto_completo.pdf Versión publicada 94654 http://zaguan.unizar.es/record/60650/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:60650 articulos driver 2017-12-21-08:59:47 ARTICLE