000060682 001__ 60682
000060682 005__ 20190709135456.0
000060682 0247_ $$2doi$$a10.1038/ncomms14281
000060682 0248_ $$2sideral$$a98244
000060682 037__ $$aART-2017-98244
000060682 041__ $$aeng
000060682 100__ $$aSetaro, A.
000060682 245__ $$aPreserving p-conjugation in covalently functionalized carbon nanotubes for optoelectronic applications
000060682 260__ $$c2017
000060682 5060_ $$aAccess copy available to the general public$$fUnrestricted
000060682 5203_ $$aCovalent functionalization tailors carbon nanotubes for a wide range of applications in varying environments. Its strength and stability of attachment come at the price of degrading the carbon nanotubes sp 2 network and destroying the tubes electronic and optoelectronic features. Here we present a non-destructive, covalent, gram-scale functionalization of single-walled carbon nanotubes by a new 2+1] cycloaddition. The reaction rebuilds the extended p-network, thereby retaining the outstanding quantum optoelectronic properties of carbon nanotubes, including bright light emission at high degree of functionalization (1 group per 25 carbon atoms). The conjugation method described here opens the way for advanced tailoring nanotubes as demonstrated for light-triggered reversible doping through photochromic molecular switches and nanoplasmonic gold-nanotube hybrids with enhanced infrared light emission.
000060682 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/FIS2013-46159-C3-3-P$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 696656-GrapheneCore1$$9info:eu-repo/grantAgreement/EC/H2020/696656/EU/Graphene-based disruptive technologies/GrapheneCore1$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 642742-Enabling Excellence$$9info:eu-repo/grantAgreement/EC/H2020/642742/EU/Graphene-based nanomaterials for touchscreen technologies: Comprehension, Commerce and Communication/Enabling Excellence$$9info:eu-repo/grantAgreement/EC/FP7/604391/EU/Graphene-Based Revolutions in ICT And Beyond/GRAPHENE$$9info:eu-repo/grantAgreement/EC/FP7/312483/EU/Enabling Science and Technology through European Electron Microscopy/ESTEEM 2$$9info:eu-repo/grantAgreement/ES/DGA/E26
000060682 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000060682 590__ $$a12.353$$b2017
000060682 591__ $$aMULTIDISCIPLINARY SCIENCES$$b3 / 64 = 0.047$$c2017$$dQ1$$eT1
000060682 592__ $$a6.582$$b2017
000060682 593__ $$aBiochemistry, Genetics and Molecular Biology (miscellaneous)$$c2017$$dQ1
000060682 593__ $$aPhysics and Astronomy (miscellaneous)$$c2017$$dQ1
000060682 593__ $$aChemistry (miscellaneous)$$c2017$$dQ1
000060682 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000060682 700__ $$aAdeli, M.
000060682 700__ $$aGlaeske, M.
000060682 700__ $$aPrzyrembel, D.
000060682 700__ $$aBisswanger, T.
000060682 700__ $$aGordeev, G.
000060682 700__ $$aMaschietto, F.
000060682 700__ $$aFaghani, A.
000060682 700__ $$aPaulus, B.
000060682 700__ $$aWeinelt, M.
000060682 700__ $$0(orcid)0000-0002-2071-9093$$aArenal, R.$$uUniversidad de Zaragoza
000060682 700__ $$aHaag, R.
000060682 700__ $$aReich, S.
000060682 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDpto. Física Materia Condensa.$$cÁrea Física Materia Condensada
000060682 773__ $$g8 (2017), [7 pp]$$pNATURE COMMUNICATIONS$$tNature Communications$$x2041-1723
000060682 8564_ $$s2218522$$uhttps://zaguan.unizar.es/record/60682/files/texto_completo.pdf$$yVersión publicada
000060682 8564_ $$s62720$$uhttps://zaguan.unizar.es/record/60682/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000060682 909CO $$ooai:zaguan.unizar.es:60682$$particulos$$pdriver
000060682 951__ $$a2019-07-09-11:43:39
000060682 980__ $$aARTICLE