60725 20200221144128.0 doi 10.1016/j.micromeso.2015.12.004 sideral 93261 ART-2016-93261 eng (orcid)0000-0003-1273-2690 Sorribas, S. Synthesis and gas adsorption properties of mesoporous silica-NH2-MIL-53(Al) core-shell spheres 2016 Access copy available to the general public Unrestricted Ordered mesoporous silica-NH2-MIL-53(Al) core-shell spheres of about 4 µm in diameter have been synthesized by seeding the corresponding mesoporous silica spheres (MSSs) with crystals of NH2-MIL-53(Al) and subsequent secondary crystal growth into a MOF shell. The morphology of the particles was analyzed by SEM, while TGA, EDX and XRD characterizations gave information on the composition and structure of this material and the activation of the MOF. N2 adsorption analysis revealed that the NH2-MIL-53(Al) shell controlled the access of guest molecules into the hydrophilic silica mesoporous structure, while the breathing behavior of the microporous NH2-MIL-53(Al) shell was confirmed by CO2 adsorption isotherms. info:eu-repo/grantAgreement/ES/MINECO/MAT2013-40566-R info:eu-repo/semantics/openAccess by-nc-nd http://creativecommons.org/licenses/by-nc-nd/3.0/es/ 3.615 2016 MATERIALS SCIENCE, MULTIDISCIPLINARY 57 / 275 = 0.207 2016 Q1 T1 CHEMISTRY, APPLIED 10 / 72 = 0.139 2016 Q1 T1 NANOSCIENCE & NANOTECHNOLOGY 32 / 87 = 0.368 2016 Q2 T2 CHEMISTRY, PHYSICAL 43 / 145 = 0.297 2016 Q2 T1 1.093 2016 Chemistry (miscellaneous) 2016 Q1 Condensed Matter Physics 2016 Q1 Materials Science (miscellaneous) 2016 Q1 Mechanics of Materials 2016 Q1 Nanoscience and Nanotechnology 2016 Q2 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion (orcid)0000-0002-9934-1707 Zornoza, B. Serra-Crespo, P. Gascon, J. Kapteijn, F. (orcid)0000-0002-4954-1188 Téllez, C. Universidad de Zaragoza (orcid)0000-0003-1512-4500 Coronas, J. Universidad de Zaragoza 5005 555 Universidad de Zaragoza Dpto. Ing.Quím.Tecnol.Med.Amb. Área Ingeniería Química 225 (2016), 116-121 Microporous mesoporous mater. MICROPOROUS AND MESOPOROUS MATERIALS 1387-1811 1603646 http://zaguan.unizar.es/record/60725/files/texto_completo.pdf Postprint 63603 http://zaguan.unizar.es/record/60725/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:60725 articulos driver 2020-02-21-13:04:23 ARTICLE