000060966 001__ 60966
000060966 005__ 20190709135500.0
000060966 0247_ $$2doi$$a10.1039/c6sc05122g
000060966 0248_ $$2sideral$$a98501
000060966 037__ $$aART-2017-98501
000060966 041__ $$aeng
000060966 100__ $$aGiménez-Marqués, M.
000060966 245__ $$aGas confinement in compartmentalized coordination polymers for highly selective sorption
000060966 260__ $$c2017
000060966 5060_ $$aAccess copy available to the general public$$fUnrestricted
000060966 5203_ $$aDiscrimination between different gases is an essential aspect for industrial and environmental applications involving sensing and separation. Several classes of porous materials have been used in this context, including zeolites and more recently MOFs. However, to reach high selectivities for the separation of gas mixtures is a challenging task that often requires the understanding of the specific interactions established between the porous framework and the gases. Here we propose an approach to obtain an enhanced selectivity based on the use of compartmentalized coordination polymers, named CCP-1 and CCP-2, which are crystalline materials comprising isolated discrete cavities. These compartmentalized materials are excellent candidates for the selective separation of CO2 from methane and nitrogen. A complete understanding of the sorption process is accomplished with the use of complementary experimental techniques including X-ray diffraction, adsorption studies, inelastic- and quasi-elastic neutron scattering, magnetic measurements and molecular dynamics calculations.
000060966 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/SEV-2012-0267$$9info:eu-repo/grantAgreement/ES/MINECO/MDM-2015-0538$$9info:eu-repo/grantAgreement/ES/MINECO/MAT2015-71842-P$$9info:eu-repo/grantAgreement/ES/MINECO/MAT2014-56143-R$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ-2014-59209-P$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 724681-S-CAGE$$9info:eu-repo/grantAgreement/EC/H2020/724681/EU/Smart Coordination Polymers with Compartmentalized Pockets for Adaptive Guest Entrance/S-CAGE$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 658224-hetero-MOF$$9info:eu-repo/grantAgreement/EC/H2020/658224/EU/Rational design of novel heterometallic MOFs for their use in heterogeneous catalysis for cascade reactions/hetero-MOF
000060966 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/
000060966 590__ $$a9.063$$b2017
000060966 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b18 / 171 = 0.105$$c2017$$dQ1$$eT1
000060966 592__ $$a4.508$$b2017
000060966 593__ $$aChemistry (miscellaneous)$$c2017$$dQ1
000060966 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000060966 700__ $$aCalvo Galve, N.
000060966 700__ $$aPalomino, M.
000060966 700__ $$aValencia, S.
000060966 700__ $$aRey, F.
000060966 700__ $$aSastre, G.
000060966 700__ $$aVitórica-Yrezábal, I. J.
000060966 700__ $$aJiménez-Ruiz, M.
000060966 700__ $$0(orcid)0000-0002-8505-5232$$aRodríguez-Velamazán, J. A.
000060966 700__ $$aGonzález, M. A.
000060966 700__ $$aJordá, J. L.
000060966 700__ $$aCoronado, E.
000060966 700__ $$aEspallargas, G. M.
000060966 773__ $$g8, 4 (2017), 3109-3120$$pChem. sci.$$tCHEMICAL SCIENCE$$x2041-6520
000060966 8564_ $$s1218023$$uhttps://zaguan.unizar.es/record/60966/files/texto_completo.pdf$$yVersión publicada
000060966 8564_ $$s116929$$uhttps://zaguan.unizar.es/record/60966/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000060966 909CO $$ooai:zaguan.unizar.es:60966$$particulos$$pdriver
000060966 951__ $$a2019-07-09-11:46:22
000060966 980__ $$aARTICLE