61549 20201113085627.0 doi 10.1039/c6dt02652d sideral 98922 ART-2016-98922 eng (orcid)0000-0002-3600-1721 Campo Ruiz, Jesus Javier Universidad de Zaragoza A symmetric, triply interlaced 3-D anionic MOF that exhibits both magnetic order and SMM behaviour 2016 Access copy available to the general public Unrestricted A newly prepared 3-D polymer of cobalt citrate cubanes bridged by high-spin Co(II) centres displays both single-molecule magnet (SMM) behaviour and magnetic ordering. Triple interpenetration of the 3-D diamondoid polymers yields a crystalline solid with channels that host cations and free water molecules, with the SMM behaviour of the Co4O4 cores preserved. The octahedrally coordinated Co(II) bridges are implicated in the onset of magnetic order at an experimentally accessible temperature. info:eu-repo/grantAgreement/ES/DGA/M4 info:eu-repo/grantAgreement/ES/MEC/FPU-AP2009-4211 info:eu-repo/grantAgreement/ES/MINECO/MAT2015-68200-C2-1-P info:eu-repo/grantAgreement/ES/MINECO/MAT2015-68200-C2-2-P info:eu-repo/semantics/openAccess by-nc http://creativecommons.org/licenses/by-nc/3.0/es/ 4.029 2016 CHEMISTRY, INORGANIC & NUCLEAR 7 / 46 = 0.152 2016 Q1 T1 1.229 2016 Inorganic Chemistry 2016 Q1 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion (orcid)0000-0002-0444-996X Falvello, Lawrence Rocco Universidad de Zaragoza (orcid)0000-0001-8461-6846 Forcén, Elena Sáenz de Pipaón, Cristina (orcid)0000-0002-6403-7270 Palacio, Fernando Universidad de Zaragoza Tomás, Milagros 2010 760 Universidad de Zaragoza Dpto. Química Inorgánica Área Química Inorgánica 2003 395 Universidad de Zaragoza Dpto. Física Materia Condensa. Área Física Materia Condensada 45 (2016), 16764 [5 pp] Dalton Trans. Dalton Transactions 1477-9226 2449634 http://zaguan.unizar.es/record/61549/files/texto_completo.pdf Versión publicada 60761 http://zaguan.unizar.es/record/61549/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:61549 articulos driver 2020-11-13-08:46:31 ARTICLE