000061939 001__ 61939
000061939 005__ 20200221144229.0
000061939 0247_ $$2doi$$a10.1039/c6dt03047e
000061939 0248_ $$2sideral$$a97353
000061939 037__ $$aART-2016-97353
000061939 041__ $$aeng
000061939 100__ $$aBartual-Murgui , C.
000061939 245__ $$aDesigned intramolecular blocking of the spin crossover of an Fe(II) complex
000061939 260__ $$c2016
000061939 5060_ $$aAccess copy available to the general public$$fUnrestricted
000061939 5203_ $$aA ligand derived from 1,3bpp (2-(pyrazol-1-yl)-6-(pyrazol-3-yl)- pyridine) has been prepared to prove that the spin crossover (SCO) of an Fe(II) complex can be blocked by means of intramolecular interactions not related to the crystal field. Calculations show that the blocking is caused by the energy penalty incurred by the rotation of a phenyl ring, needed to avoid steric hindrance upon SCO.
000061939 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/MAT2014-53961-R$$9info:eu-repo/grantAgreement/ES/MINECO/MAT2015-70868-ERC
000061939 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000061939 590__ $$a4.029$$b2016
000061939 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b7 / 46 = 0.152$$c2016$$dQ1$$eT1
000061939 592__ $$a1.229$$b2016
000061939 593__ $$aInorganic Chemistry$$c2016$$dQ1
000061939 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000061939 700__ $$aVela , S.
000061939 700__ $$0(orcid)0000-0003-2095-5843$$aRoubeau , Olivier Stephane$$uUniversidad de Zaragoza
000061939 700__ $$aAromí , G
000061939 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDpto. Física Materia Condensa.$$cÁrea Física Materia Condensada
000061939 773__ $$g45 (2016), 14058-14062$$pDalton Trans.$$tDalton Transactions$$x1477-9226
000061939 8564_ $$s1015080$$uhttps://zaguan.unizar.es/record/61939/files/texto_completo.pdf$$yVersión publicada
000061939 8564_ $$s113455$$uhttps://zaguan.unizar.es/record/61939/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000061939 909CO $$ooai:zaguan.unizar.es:61939$$particulos$$pdriver
000061939 951__ $$a2020-02-21-13:18:41
000061939 980__ $$aARTICLE