000062047 001__ 62047
000062047 005__ 20171215082712.0
000062047 0247_ $$2doi$$a10.1021/om2005782
000062047 0248_ $$2sideral$$a74695
000062047 037__ $$aART-2011-74695
000062047 041__ $$aeng
000062047 100__ $$aPalacios, Laura
000062047 245__ $$aSynthesis of a square-planar rhodium alkylidene N-heterocyclic carbene complex and its reactivity toward alkenes
000062047 260__ $$c2011
000062047 5060_ $$aAccess copy available to the general public$$fUnrestricted
000062047 5203_ $$aThe first rhodium alkylidene square-planar complex stabilized by an N-heterocyclic carbene ligand, RhCl(-CHPh)(IPr)PPh3 (2; IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-carbene), has been prepared by reaction of RhCl(IPr)(PPh3)2 (1) with phenyldiazomethane and its dynamic behavior in solution studied. Treatment of 2 with alkenes results in the formation of the ¿2-olefin complexes RhCl(¿2-CH2-CHR)(IPr)PPh3 (3, R = H; 4, R = Ph; 5, R = OEt) and new olefins arising from the coupling of the alkylidene with the alkenes, likely via a metallacyclobutane intermediate.
000062047 536__ $$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2010-15221$$9info:eu-repo/grantAgreement/ES/MINECO/Consolider-Ingenio/CSD2006-0015$$9info:eu-repo/grantAgreement/ES/MICINN-FEDER/CSD2009-00050$$9info:eu-repo/grantAgreement/ES/DGA/E07
000062047 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000062047 590__ $$a3.963$$b2011
000062047 591__ $$aCHEMISTRY, ORGANIC$$b10 / 56 = 0.179$$c2011$$dQ1$$eT1
000062047 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b6 / 44 = 0.136$$c2011$$dQ1$$eT1
000062047 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000062047 700__ $$aMiao, Xiaowei
000062047 700__ $$aDi Giuseppe, Andrea
000062047 700__ $$aPascal, Simon.
000062047 700__ $$aCunchillos, Carmen
000062047 700__ $$aCastarlenas, Ricardo
000062047 700__ $$aPérez-Torrente, Jesús-José
000062047 700__ $$aLahoz, Fernando J..
000062047 700__ $$aDixneuf, Pierre H.
000062047 700__ $$aOro, Luis A.
000062047 773__ $$g30, 19 (2011), [16 pp.]$$pOrganometallics$$tOrganometallics$$x0276-7333
000062047 8564_ $$s567459$$uhttps://zaguan.unizar.es/record/62047/files/texto_completo.pdf$$yPostprint
000062047 8564_ $$s59771$$uhttps://zaguan.unizar.es/record/62047/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000062047 909CO $$ooai:zaguan.unizar.es:62047$$particulos$$pdriver
000062047 951__ $$a2017-12-15-08:22:15
000062047 980__ $$aARTICLE