000062835 001__ 62835
000062835 005__ 20200221144302.0
000062835 0247_ $$2doi$$a10.1002/chem.201601530
000062835 0248_ $$2sideral$$a101459
000062835 037__ $$aART-2016-101459
000062835 041__ $$aeng
000062835 100__ $$aCacho Bailo, Fernando
000062835 245__ $$aInteractive thermal effects on metal–organic framework Polymer composite membranes
000062835 260__ $$c2016
000062835 5060_ $$aAccess copy available to the general public$$fUnrestricted
000062835 5203_ $$aPolymeric membranes are important tools for intensifying separation processes in chemical industries, concerning strategic tasks such as CO2 sequestration, H2 production, and water supply and disposal. Mixed-matrix and supported membranes have been widely developed; recently many of them have been based on metal–organic frameworks (MOFs). However, most of the impacts MOFs have within the polymer matrix have yet to be determined. The effects related to thermal behavior arising from the combination of MOF ZIF-8 and polysulfone have now been quantified. The catalyzed oxidation of the polymer is strongly affected by the MOF crystal size and distribution inside the membrane. A 16 wt¿% 140 nm-sized ZIF-8 loading causes a 40¿% decrease in the observed activation energy of the polysulfone oxidation that takes place at a temperature (545¿°C) 80¿°C lower than in the raw polymer (625¿°C).
000062835 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/MAT2013-40566-R$$9info:eu-repo/grantAgreement/ES/DGA/T05
000062835 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000062835 590__ $$a5.317$$b2016
000062835 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b29 / 166 = 0.175$$c2016$$dQ1$$eT1
000062835 592__ $$a2.351$$b2016
000062835 593__ $$aChemistry (miscellaneous)$$c2016$$dQ1
000062835 655_4 $$ainfo:eu-repo/semantics/conferenceObject$$vinfo:eu-repo/semantics/acceptedVersion
000062835 700__ $$aTéllez, Carlos
000062835 700__ $$aCoronas, Joaquín
000062835 773__ $$g22, 28 (2016), [5 pp.]$$pChemistry (Weinh.)$$tChemistry - A European Journal$$x0947-6539
000062835 8564_ $$s531823$$uhttps://zaguan.unizar.es/record/62835/files/texto_completo.pdf$$yPostprint
000062835 8564_ $$s135129$$uhttps://zaguan.unizar.es/record/62835/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000062835 909CO $$ooai:zaguan.unizar.es:62835$$particulos$$pdriver
000062835 951__ $$a2020-02-21-13:32:48
000062835 980__ $$aARTICLE