62835 20200221144302.0 doi 10.1002/chem.201601530 sideral 101459 ART-2016-101459 eng Cacho Bailo, Fernando Interactive thermal effects on metal–organic framework Polymer composite membranes 2016 Access copy available to the general public Unrestricted Polymeric membranes are important tools for intensifying separation processes in chemical industries, concerning strategic tasks such as CO2 sequestration, H2 production, and water supply and disposal. Mixed-matrix and supported membranes have been widely developed; recently many of them have been based on metal–organic frameworks (MOFs). However, most of the impacts MOFs have within the polymer matrix have yet to be determined. The effects related to thermal behavior arising from the combination of MOF ZIF-8 and polysulfone have now been quantified. The catalyzed oxidation of the polymer is strongly affected by the MOF crystal size and distribution inside the membrane. A 16 wt¿% 140 nm-sized ZIF-8 loading causes a 40¿% decrease in the observed activation energy of the polysulfone oxidation that takes place at a temperature (545¿°C) 80¿°C lower than in the raw polymer (625¿°C). info:eu-repo/grantAgreement/ES/MINECO/MAT2013-40566-R info:eu-repo/grantAgreement/ES/DGA/T05 info:eu-repo/semantics/openAccess All rights reserved http://www.europeana.eu/rights/rr-f/ 5.317 2016 CHEMISTRY, MULTIDISCIPLINARY 29 / 166 = 0.175 2016 Q1 T1 2.351 2016 Chemistry (miscellaneous) 2016 Q1 info:eu-repo/semantics/conferenceObject info:eu-repo/semantics/acceptedVersion Téllez, Carlos Coronas, Joaquín 22, 28 (2016), [5 pp.] Chemistry (Weinh.) Chemistry - A European Journal 0947-6539 531823 http://zaguan.unizar.es/record/62835/files/texto_completo.pdf Postprint 135129 http://zaguan.unizar.es/record/62835/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:62835 articulos driver 2020-02-21-13:32:48 ARTICLE