63042 20200623125808.0 doi 10.1021/acsomega.7b00138 sideral 101730 ART-2017-101730 eng (orcid)0000-0001-6028-5499 Vellé, A. Universidad de Zaragoza From Imidazole toward Imidazolium Salts and N-Heterocyclic Carbene Ligands: Electronic and Geometrical Redistribution 2017 Access copy available to the general public Unrestricted Investigations dealing with N-heterocyclic carbenes and their derivatives are usually centered on the influence that they exert by acting as catalysts, ionic liquids, or metallodrugs and consequently on their capabilities to tune the properties and reactivity of these systems. In this context, we aimed to focus on the internal molecular changes undergone by imidazole derivatives, from electronic and geometrical points of view. This work represents an empirical evidence of the molecular modifications that an imidazole skeleton undergoes upon protonation, alkylation, and metalation. info:eu-repo/grantAgreement/ES/UZ/UZ2015-CIE-09 info:eu-repo/semantics/openAccess by-nc http://creativecommons.org/licenses/by-nc/3.0/es/ 0.749 2017 Chemical Engineering (miscellaneous) 2017 Q1 Chemistry (miscellaneous) 2017 Q2 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion (orcid)0000-0003-3305-4219 Cebollada, A. (orcid)0000-0003-2299-9428 Macías, R. Universidad de Zaragoza (orcid)0000-0003-3144-5320 Iglesias, M. Gil-Moles, M. (orcid)0000-0002-8220-6031 Sanz Miguel, P.J. Universidad de Zaragoza 2010 760 Universidad de Zaragoza Dpto. Química Inorgánica Área Química Inorgánica 2, 4 (2017), 1392-1399 ACS Omega ACS OMEGA 2470-1343 1388242 http://zaguan.unizar.es/record/63042/files/texto_completo.pdf Versión publicada 120624 http://zaguan.unizar.es/record/63042/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:63042 articulos driver 2020-06-23-12:28:19 ARTICLE