000063345 001__ 63345
000063345 005__ 20200221144302.0
000063345 0247_ $$2doi$$a10.1039/C5CE02526E
000063345 0248_ $$2sideral$$a101186
000063345 037__ $$aART-2016-101186
000063345 041__ $$aeng
000063345 100__ $$0(orcid)0000-0002-0769-7168$$aAlegre-Requena, Juan V.
000063345 245__ $$aMetal-organic frameworks (MOFs) bring new life to hydrogen-bonding organocatalysts in confined spaces
000063345 260__ $$c2016
000063345 5060_ $$aAccess copy available to the general public$$fUnrestricted
000063345 5203_ $$aHydrogen-bonding organocatalysis has emerged as a promising biomimetic alternative to Lewis acid catalysis. Urea, thiourea and squaramide moieties represent the most common hydrogen-bond donors used for the preparation of these catalysts. However, their significant tendency to undergo self-quenching (self-aggregation) often decreases their solubility and reactivity. Recently, scientists have found a promising way around this problem by immobilizing the hydrogen-bonding organocatalysts on metal–organic frameworks (MOFs). Along with advantageous modular synthesis and recycling properties, the tunable porosity and topology of MOFs also allows fast mass transport and/or interactions with substrates. Herein, we highlight the existing examples dealing with the fabrication and testing of hydrogen-bonding organocatalyst-containing MOFs, providing also our vision for further advances in this area. The results derived from these studies will likely serve as inspiration for the future development of superior hydrogen-bonding organocatalysts to accomplish in confined spaces chemical transformations that are either slow or unaffordable under standard homogeneous conditions.
000063345 536__ $$9info:eu-repo/grantAgreement/ES/CSIC/PIE-201580I010$$9info:eu-repo/grantAgreement/ES/DGA/E104$$9info:eu-repo/grantAgreement/ES/UZ/JIUZ-2014-CIE-07
000063345 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000063345 590__ $$a3.474$$b2016
000063345 591__ $$aCRYSTALLOGRAPHY$$b5 / 26 = 0.192$$c2016$$dQ1$$eT1
000063345 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b49 / 166 = 0.295$$c2016$$dQ2$$eT1
000063345 592__ $$a1.052$$b2016
000063345 593__ $$aChemistry (miscellaneous)$$c2016$$dQ1
000063345 593__ $$aMaterials Science (miscellaneous)$$c2016$$dQ1
000063345 593__ $$aCondensed Matter Physics$$c2016$$dQ1
000063345 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000063345 700__ $$0(orcid)0000-0001-6832-8983$$aMarqués-López, María Eugenia$$uUniversidad de Zaragoza
000063345 700__ $$0(orcid)0000-0002-5244-9569$$aHerrera, Raquel P.$$uUniversidad de Zaragoza
000063345 700__ $$aDíaz Díaz, David
000063345 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000063345 773__ $$g18, 22 (2016), 3985-3995$$pCrystEngComm$$tCRYSTENGCOMM$$x1466-8033
000063345 8564_ $$s1519744$$uhttps://zaguan.unizar.es/record/63345/files/texto_completo.pdf$$yPostprint
000063345 8564_ $$s123576$$uhttps://zaguan.unizar.es/record/63345/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000063345 909CO $$ooai:zaguan.unizar.es:63345$$particulos$$pdriver
000063345 951__ $$a2020-02-21-13:32:53
000063345 980__ $$aARTICLE