Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III) ß-Diketonate Complexes
Resumen: Two novel europium(III) complexes, a monomer and a homodimer, with 1-(4-chlorophenyl)-4,4,4-trifluoro-1,3-butanedione (Hcbtfa) and 5-chloro-1,10-phenanthroline (cphen) ligands, formulated as [Eu(cbtfa)3(cphen)] and [Eu2(cbtfa)4(cphen)2(CH3O)2], have been synthesized. Their structures have been elucidated by X-ray diffraction and their absorption and emission properties have been studied in the solid state. The experimental data has then been used to test the recently released LUMPAC software, a promising tool which can facilitate the design of more efficient lanthanide light-conversion molecular devices by combining ground state geometry, excited state energy, and luminescent properties calculations.
Idioma: Inglés
DOI: 10.1155/2015/205047
Año: 2015
Publicado en: ADVANCES IN CONDENSED MATTER PHYSICS 2015 (2015), 205047 [12 pp]
ISSN: 1687-8108

Factor impacto JCR: 0.932 (2015)
Categ. JCR: PHYSICS, CONDENSED MATTER rank: 51 / 67 = 0.761 (2015) - Q4 - T3
Factor impacto SCIMAGO: 0.312 - Condensed Matter Physics (Q3)

Tipo y forma: Article (Published version)
Área (Departamento): Area Ingeniería Agroforestal (Dpto. CC.Agrar.y Medio Natural)

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