Insight into the reversible structural crystalline-state transformation from MIL-53(Al) to MIL-68(Al)

Perea-Cachero, A. (Universidad de Zaragoza) ; Romero, E. (Universidad de Zaragoza) ; Téllez, C. (Universidad de Zaragoza) ; Coronas, J. (Universidad de Zaragoza)
Insight into the reversible structural crystalline-state transformation from MIL-53(Al) to MIL-68(Al)
Resumen: The reversible crystalline transformation between MIL-53(Al) and MIL-68(Al) is described. This followed a uniform conversion model with cleavage and formation of metal-ligand bonds after exchange or removal of guest molecules. MIL-68(Al) materials produced during the transformations had higher thermal stability and crystallinity than the as-synthesized MIL-68(Al).
Idioma: Inglés
DOI: 10.1039/c7ce02034a
Año: 2018
Publicado en: CRYSTENGCOMM 20, 4 (2018), 402-406
ISSN: 1466-8033

Factor impacto JCR: 3.382 (2018)
Categ. JCR: CRYSTALLOGRAPHY rank: 5 / 25 = 0.2 (2018) - Q1 - T1
Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 57 / 172 = 0.331 (2018) - Q2 - T2

Financiación: info:eu-repo/grantAgreement/ES/DGA/T05
Financiación: info:eu-repo/grantAgreement/ES/MINECO/MAT2013-40556-R
Financiación: info:eu-repo/grantAgreement/ES/MINECO/MAT2016-77290-R
Tipo y forma: Article (Published version)
Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)

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