000070348 001__ 70348
000070348 005__ 20200221144222.0
000070348 0247_ $$2doi$$a10.1016/j.apcata.2016.09.018
000070348 0248_ $$2sideral$$a96708
000070348 037__ $$aART-2016-96708
000070348 041__ $$aeng
000070348 100__ $$0(orcid)0000-0002-8556-3587$$aLópez, A.
000070348 245__ $$aPt-CoOx nanoparticles supported on ETS-10 for preferential oxidation of CO reaction
000070348 260__ $$c2016
000070348 5060_ $$aAccess copy available to the general public$$fUnrestricted
000070348 5203_ $$aIn this paper we prepare bimetallic Pt-CoOx nanoparticles which are further supported in microporous titanosilicate ETS-10. This support has been previously demonstrated as a good candidate for this reaction in the presence of CO2 and H2O. The bimetallic nanoparticles and the supported catalysts containing different loadings of nanoparticles have been extensively characterized and tested in the PROX reaction. The characterization of the nanoparticles discarded the formation of a metallic alloy, although Co and Pt are intimately in contact in the nanoparticle as the HAADF-STEM images revealed. XPS confirmed that the calcined nanoparticles would consist of metallic platinum and cobalt and Pt oxides. The catalyst containing 1.4 wt.% of PtCo nanoparticles can achieve complete CO conversion in the temperature range 120–150 °C working at WHSV = 30 L h-1 g-1.
000070348 536__ $$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/PRI-PIBAR-2011-1349
000070348 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000070348 590__ $$a4.339$$b2016
000070348 591__ $$aENVIRONMENTAL SCIENCES$$b30 / 229 = 0.131$$c2016$$dQ1$$eT1
000070348 591__ $$aCHEMISTRY, PHYSICAL$$b34 / 145 = 0.234$$c2016$$dQ1$$eT1
000070348 592__ $$a1.202$$b2016
000070348 593__ $$aProcess Chemistry and Technology$$c2016$$dQ1
000070348 593__ $$aCatalysis$$c2016$$dQ2
000070348 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000070348 700__ $$0(orcid)0000-0003-3363-2912$$aNavascues, N.
000070348 700__ $$0(orcid)0000-0002-4758-9380$$aMallada, R.$$uUniversidad de Zaragoza
000070348 700__ $$0(orcid)0000-0002-2966-9088$$aIrusta, S.$$uUniversidad de Zaragoza
000070348 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000070348 773__ $$g528 (2016), 86-92$$pAppl. catal., A Gen.$$tAPPLIED CATALYSIS A-GENERAL$$x0926-860X
000070348 8564_ $$s664981$$uhttps://zaguan.unizar.es/record/70348/files/texto_completo.pdf$$yPostprint
000070348 8564_ $$s51368$$uhttps://zaguan.unizar.es/record/70348/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000070348 909CO $$ooai:zaguan.unizar.es:70348$$particulos$$pdriver
000070348 951__ $$a2020-02-21-13:15:44
000070348 980__ $$aARTICLE