doi:10.1039/c6cc09133dengIturmendi, AmaiaIglesias, ManuelMunárriz, JulenPolo, VíctorPérez-Torrente, Jesús J.Oro, Luis A.Efficient preparation of carbamates by Rh-catalysed oxidative carbonylation: Unveiling the role of the oxidantART-2017-97871The synthesis of a wide variety of carbamates from amines, alcohols and carbon monoxide has been achieved by means of a Rh-catalysed oxidative carbonylation reaction that uses Oxone as a stoichiometric oxidant. In-depth studies on the reaction mechanism shed light on the intimate role of Oxone in the catalytic cycle.2017http://zaguan.unizar.es/record/7077310.1039/c6cc09133dhttp://zaguan.unizar.es/record/70773oai:zaguan.unizar.es:70773info:eu-repo/grantAgreement/ES/DGA/E07info:eu-repo/grantAgreement/ES/MINECO/Consolider-Ingenio/CSD2009-0050info:eu-repo/grantAgreement/ES/MINECO/CTQ2013-42532-Pinfo:eu-repo/grantAgreement/ES/MINECO/CTQ2015-67366-PChemical Communications 53, 2 (2017), 404-407All rights reservedhttp://www.europeana.eu/rights/rr-f/info:eu-repo/semantics/openAccess