000070837 001__ 70837
000070837 005__ 20190709135529.0
000070837 0247_ $$2doi$$a10.1016/j.jct.2017.03.027
000070837 0248_ $$2sideral$$a98543
000070837 037__ $$aART-2017-98543
000070837 041__ $$aeng
000070837 100__ $$0(orcid)0000-0001-6182-2196$$aMartínez-López, J. F.$$uUniversidad de Zaragoza
000070837 245__ $$aIsobaric molar heat capacities of the mixture (p-cymene + ethanol) at several temperatures and atmospheric pressure
000070837 260__ $$c2017
000070837 5060_ $$aAccess copy available to the general public$$fUnrestricted
000070837 5203_ $$aExperimental isobaric molar heat capacities at atmospheric pressure have been determined every 10 K for the mixture p-cymene (1) + ethanol (2) in the temperature interval (298.6–328.4) K over the whole composition range with a Calvet type calorimeter. Densities, necessary for calculating heat capacities, have been also measured in the same conditions. Excess molar volumes have been calculated from densities. Excess molar heat capacities have been calculated from the molar heat capacities, their values being positive and increasing as the temperature rises. Excess properties are discussed in terms of intermolecular interactions. The solvation model COSMO-RS has been applied to predict the excess molar heat capacities. The model predicts fairly well the values of the excess heat capacities.
000070837 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E52$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-64049-C3-2-R
000070837 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000070837 590__ $$a2.631$$b2017
000070837 591__ $$aTHERMODYNAMICS$$b14 / 59 = 0.237$$c2017$$dQ1$$eT1
000070837 591__ $$aCHEMISTRY, PHYSICAL$$b74 / 146 = 0.507$$c2017$$dQ3$$eT2
000070837 592__ $$a1.067$$b2017
000070837 593__ $$aAtomic and Molecular Physics, and Optics$$c2017$$dQ1
000070837 593__ $$aPhysical and Theoretical Chemistry$$c2017$$dQ1
000070837 593__ $$aMaterials Science (miscellaneous)$$c2017$$dQ1
000070837 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000070837 700__ $$0(orcid)0000-0002-0661-9889$$aPardo, J. I.$$uUniversidad de Zaragoza
000070837 700__ $$0(orcid)0000-0001-7569-5036$$aUrieta, J. S.
000070837 700__ $$0(orcid)0000-0001-9379-8047$$aMainar, A. M.$$uUniversidad de Zaragoza
000070837 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física
000070837 773__ $$g111 (2017), 142-148$$pJ. Chem. Thermodyn.$$tJournal of Chemical Thermodynamics$$x0021-9614
000070837 8564_ $$s349327$$uhttps://zaguan.unizar.es/record/70837/files/texto_completo.pdf$$yPostprint
000070837 8564_ $$s65390$$uhttps://zaguan.unizar.es/record/70837/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000070837 909CO $$ooai:zaguan.unizar.es:70837$$particulos$$pdriver
000070837 951__ $$a2019-07-09-12:01:06
000070837 980__ $$aARTICLE