000071169 001__ 71169
000071169 005__ 20221027132638.0
000071169 0247_ $$2doi$$a10.1039/c7gc01583f
000071169 0248_ $$2sideral$$a102107
000071169 037__ $$aART-2017-102107
000071169 041__ $$aeng
000071169 100__ $$0(orcid)0000-0002-3256-2089$$aLeal-Duaso, Alejandro
000071169 245__ $$aSynthesis of 3-alkoxypropan-1,2-diols from glycidol: experimental and theoretical studies for the optimization of the synthesis of glycerol derived solvents
000071169 260__ $$c2017
000071169 5060_ $$aAccess copy available to the general public$$fUnrestricted
000071169 5203_ $$aA straightforward synthetic methodology has been derived for the synthesis of glycerol monoethers from glycidol and alcohols. Several homogeneous and heterogeneous basic catalysts have been tested, the best results being obtained with readily available and inexpensive alkaline metal hydroxides. In the best case, good yield of the desired monoether is obtained under smooth reaction conditions, always with total conversion of glycidol. The selectivity of the reactions mainly depends on the alcohol used, due to the concurrence of undesired side reactions. A mechanistic study carried out through computational DFT calculations, in which solvent effects are taken into account, also complemented the experiments, has allowed to identify the main reaction paths taking place under reaction conditions, giving insights into the main causes affecting the reaction selectivity and also into how it could be improved.
000071169 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E11$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2014-52367-R
000071169 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000071169 590__ $$a8.586$$b2017
000071169 591__ $$aGREEN & SUSTAINABLE SCIENCE & TECHNOLOGY$$b2 / 33 = 0.061$$c2017$$dQ1$$eT1
000071169 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b21 / 171 = 0.123$$c2017$$dQ1$$eT1
000071169 592__ $$a2.496$$b2017
000071169 593__ $$aPollution$$c2017$$dQ1
000071169 593__ $$aEnvironmental Chemistry$$c2017$$dQ1
000071169 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000071169 700__ $$aCaballero, M.
000071169 700__ $$0(orcid)0000-0001-9352-6922$$aUrriolabeitia, Asier
000071169 700__ $$0(orcid)0000-0003-1570-4257$$aMayoral Murillo, José Antonio$$uUniversidad de Zaragoza
000071169 700__ $$0(orcid)0000-0003-1199-2087$$aGarcía Laureiro, José Ignacio
000071169 700__ $$0(orcid)0000-0002-2676-8814$$aPires Ezquerra, María Elisabet$$uUniversidad de Zaragoza
000071169 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000071169 773__ $$g19, 17 (2017), [10 pp.]$$pGreen chem.$$tGREEN CHEMISTRY$$x1463-9262
000071169 8564_ $$s1395973$$uhttps://zaguan.unizar.es/record/71169/files/texto_completo.pdf$$yPostprint
000071169 8564_ $$s118481$$uhttps://zaguan.unizar.es/record/71169/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000071169 909CO $$ooai:zaguan.unizar.es:71169$$particulos$$pdriver
000071169 951__ $$a2022-10-27-13:09:42
000071169 980__ $$aARTICLE