000074961 001__ 74961
000074961 005__ 20200117221633.0
000074961 0247_ $$2doi$$a10.1021/acsomega.8b01352
000074961 0248_ $$2sideral$$a107709
000074961 037__ $$aART-2018-107709
000074961 041__ $$aeng
000074961 100__ $$aAliaga-Lavrijsen, M.
000074961 245__ $$aEfficient Gold(I) Acyclic Diaminocarbenes for the Synthesis of Propargylamines and Indolizines
000074961 260__ $$c2018
000074961 5060_ $$aAccess copy available to the general public$$fUnrestricted
000074961 5203_ $$aMononuclear gold(I) acyclic diaminocarbenes (ADCs) were prepared by the reaction of 1, 2-cyclohexanediamine with the corresponding isocyanide complexes [AuCl(CNR)] (R = Cy, tBu). The three-component coupling of aldehydes, amines, and alkynes was investigated by using these gold(I) ADC complexes. The new gold(I) metal complexes are highly efficient catalysts for the synthesis of propargylamines and indolizines in the absence of solvent and in mild conditions. This method affords the corresponding final products with excellent yields in short reaction times. Additionally, chiral gold(I) complexes with ADCs have been prepared and tried in the enantioselective synthesis of propargylamines.
000074961 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E07-17R$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2016-75816-C2-1-P$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2017-88091-P
000074961 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/
000074961 590__ $$a2.584$$b2018
000074961 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b75 / 172 = 0.436$$c2018$$dQ2$$eT2
000074961 592__ $$a0.754$$b2018
000074961 593__ $$aChemistry (miscellaneous)$$c2018$$dQ1
000074961 593__ $$aChemical Engineering (miscellaneous)$$c2018$$dQ1
000074961 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000074961 700__ $$0(orcid)0000-0002-5244-9569$$aPérez Herrera, R.$$uUniversidad de Zaragoza
000074961 700__ $$0(orcid)0000-0002-3978-1145$$aVillacampa, M.D.$$uUniversidad de Zaragoza
000074961 700__ $$aGimeno, M.C.
000074961 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000074961 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000074961 773__ $$g3, 8 (2018), 9805-9813$$pACS Omega$$tACS Omega$$x2470-1343
000074961 8564_ $$s1052045$$uhttps://zaguan.unizar.es/record/74961/files/texto_completo.pdf$$yVersión publicada
000074961 8564_ $$s117963$$uhttps://zaguan.unizar.es/record/74961/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000074961 909CO $$ooai:zaguan.unizar.es:74961$$particulos$$pdriver
000074961 951__ $$a2020-01-17-22:00:51
000074961 980__ $$aARTICLE