000075020 001__ 75020
000075020 005__ 20190709135509.0
000075020 0247_ $$2doi$$a10.1039/c7cp04987k
000075020 0248_ $$2sideral$$a102108
000075020 037__ $$aART-2017-102108
000075020 041__ $$aeng
000075020 100__ $$0(orcid)0000-0002-3256-2089$$aLeal-Duaso, Alejandro
000075020 245__ $$aGlycerol as a source of designer solvents: physicochemical properties of low melting mixtures containing glycerol ethers and ammonium salts
000075020 260__ $$c2017
000075020 5060_ $$aAccess copy available to the general public$$fUnrestricted
000075020 5203_ $$aIn this work we report the preparation of mixtures of several alkyl glyceryl ethers, as hydrogen bond donor compounds, with two ammonium salts, choline chloride and N,N,N-triethyl-2,3-dihydroxypropan-1-aminium chloride. The stability of the mixtures at different molar ratios and temperatures has been evaluated in order to determine the formation of low melting mixtures. Liquid and stable mixtures have been characterized and their physico-chemical properties such as density, viscosity, refractive index, conductivity and surface tension have been measured in the temperature range of 293.15 K to 343.15 K. Comparison of the mixtures prepared herein with the ones containing glycerol and choline chloride evidences the possibility of tuning the physico-chemical properties by changing the substitution pattern in the hydrogen bond donor compound or in the ammonium salt, thus broadening the scope of application of these mixtures.
000075020 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E11$$9info:eu-repo/grantAgreement/ES/MEC/FPU14-04338$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2014-52367-R
000075020 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000075020 590__ $$a3.906$$b2017
000075020 591__ $$aPHYSICS, ATOMIC, MOLECULAR & CHEMICAL$$b9 / 36 = 0.25$$c2017$$dQ1$$eT1
000075020 591__ $$aCHEMISTRY, PHYSICAL$$b46 / 146 = 0.315$$c2017$$dQ2$$eT1
000075020 592__ $$a1.686$$b2017
000075020 593__ $$aPhysics and Astronomy (miscellaneous)$$c2017$$dQ1
000075020 593__ $$aPhysical and Theoretical Chemistry$$c2017$$dQ1
000075020 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000075020 700__ $$0(orcid)0000-0002-6751-6306$$aPérez, Pascual$$uUniversidad de Zaragoza
000075020 700__ $$0(orcid)0000-0003-1570-4257$$aMayoral, José Antonio$$uUniversidad de Zaragoza
000075020 700__ $$0(orcid)0000-0002-2676-8814$$aPires, Elisabet$$uUniversidad de Zaragoza
000075020 700__ $$0(orcid)0000-0003-1199-2087$$aGarcía Laureiro, José I.
000075020 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000075020 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física
000075020 773__ $$g19, 41 (2017), [11 pp.]$$pPCCP, Phys. chem. chem. phys.$$tPHYSICAL CHEMISTRY CHEMICAL PHYSICS$$x1463-9076
000075020 8564_ $$s1495032$$uhttps://zaguan.unizar.es/record/75020/files/texto_completo.pdf$$yPostprint
000075020 8564_ $$s114883$$uhttps://zaguan.unizar.es/record/75020/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000075020 909CO $$ooai:zaguan.unizar.es:75020$$particulos$$pdriver
000075020 951__ $$a2019-07-09-11:50:44
000075020 980__ $$aARTICLE