000075600 001__ 75600
000075600 005__ 20190709135456.0
000075600 0247_ $$2doi$$a10.1016/j.ccr.2017.04.011
000075600 0248_ $$2sideral$$a99765
000075600 037__ $$aART-2017-99765
000075600 041__ $$aeng
000075600 100__ $$0(orcid)0000-0002-0497-1969$$aFernández-Alvarez, F.J.$$uUniversidad de Zaragoza
000075600 245__ $$aMonoanionic NSiN-type ligands in transition metal coordination chemistry and catalysis
000075600 260__ $$c2017
000075600 5060_ $$aAccess copy available to the general public$$fUnrestricted
000075600 5203_ $$aThe number of late transition metal complexes bearing tridentate monoanionic silyl-based NSiN-type ligands has grown in the last few years. This review describes the synthetic methodologies that allow preparation of NSiN ligands precursors as well as the chemical and structural behavior of the transition metal complexes resulting from the reaction of these ligand precursors with different metallic starting materials. In addition, a description of the catalytic processes based on Rh- and Ir-NSiN catalysts so far reported is included. Moreover, an analysis of the chemistry of iridium complexes with different fac-K 3-(Si, N, N)-NSiN ligands allows to conclude that the nature of the silyl group along with the donor ability of the nitrogen atoms at the NSiN ligands influence on the reactivity and potential catalytic activity of the respective complexes.
000075600 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E07$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-67366-P
000075600 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000075600 590__ $$a14.499$$b2017
000075600 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b1 / 45 = 0.022$$c2017$$dQ1$$eT1
000075600 592__ $$a4.342$$b2017
000075600 593__ $$aChemistry (miscellaneous)$$c2017$$dQ1
000075600 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000075600 700__ $$aLalrempuia, R.
000075600 700__ $$0(orcid)0000-0001-7154-7239$$aOro, L.A.$$uUniversidad de Zaragoza
000075600 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000075600 773__ $$g350 (2017), 49-60$$pCoord. chem. rev.$$tCOORDINATION CHEMISTRY REVIEWS$$x0010-8545
000075600 8564_ $$s1233301$$uhttps://zaguan.unizar.es/record/75600/files/texto_completo.pdf$$yPostprint
000075600 8564_ $$s42839$$uhttps://zaguan.unizar.es/record/75600/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000075600 909CO $$ooai:zaguan.unizar.es:75600$$particulos$$pdriver
000075600 951__ $$a2019-07-09-11:43:20
000075600 980__ $$aARTICLE