75600 20190709135456.0 doi 10.1016/j.ccr.2017.04.011 sideral 99765 ART-2017-99765 eng (orcid)0000-0002-0497-1969 Fernández-Alvarez, F.J. Universidad de Zaragoza Monoanionic NSiN-type ligands in transition metal coordination chemistry and catalysis 2017 Access copy available to the general public Unrestricted The number of late transition metal complexes bearing tridentate monoanionic silyl-based NSiN-type ligands has grown in the last few years. This review describes the synthetic methodologies that allow preparation of NSiN ligands precursors as well as the chemical and structural behavior of the transition metal complexes resulting from the reaction of these ligand precursors with different metallic starting materials. In addition, a description of the catalytic processes based on Rh- and Ir-NSiN catalysts so far reported is included. Moreover, an analysis of the chemistry of iridium complexes with different fac-K 3-(Si, N, N)-NSiN ligands allows to conclude that the nature of the silyl group along with the donor ability of the nitrogen atoms at the NSiN ligands influence on the reactivity and potential catalytic activity of the respective complexes. info:eu-repo/grantAgreement/ES/DGA/E07 info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-67366-P info:eu-repo/semantics/openAccess by-nc-nd http://creativecommons.org/licenses/by-nc-nd/3.0/es/ 14.499 2017 CHEMISTRY, INORGANIC & NUCLEAR 1 / 45 = 0.022 2017 Q1 T1 4.342 2017 Chemistry (miscellaneous) 2017 Q1 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Lalrempuia, R. (orcid)0000-0001-7154-7239 Oro, L.A. Universidad de Zaragoza 2010 760 Universidad de Zaragoza Dpto. Química Inorgánica Área Química Inorgánica 350 (2017), 49-60 Coord. chem. rev. COORDINATION CHEMISTRY REVIEWS 0010-8545 1233301 http://zaguan.unizar.es/record/75600/files/texto_completo.pdf Postprint 42839 http://zaguan.unizar.es/record/75600/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:75600 articulos driver 2019-07-09-11:43:20 ARTICLE