Resumen: The autothermal Chemical-Looping Reforming (a-CLR) is a process where syngas is produced with two main advantages; there are captured CO2 emissions and the heat required for the syngas production is generated by the process itself. A Ni-based material is used as oxygen carrier circulating between two fluidized bed reactors: the fuel and air reactors. In this work, the auto-thermal conditions in a global H2 production process, integrated by the a-CLR process and a Water Gas Shift reactor, using different liquid fossil fuels were theoretically determined. The hydrogen production per mol of carbon in the fuel was similar for all fossil fuels, taking a value of 2.2 at the optimal operating temperature (700 °C). In addition, the possibility of working at low temperature for a maximum H2 production was experimentally demonstrated in a continuous 1 kWth a-CLR unit. Idioma: Inglés DOI: 10.1016/j.ijhydene.2016.12.109 Año: 2017 Publicado en: International Journal of Hydrogen Energy 42, 19 (2017), 13633-13640 ISSN: 0360-3199 Factor impacto JCR: 4.229 (2017) Categ. JCR: CHEMISTRY, PHYSICAL rank: 42 / 146 = 0.288 (2017) - Q2 - T1 Categ. JCR: ENERGY & FUELS rank: 24 / 97 = 0.247 (2017) - Q1 - T1 Categ. JCR: ELECTROCHEMISTRY rank: 8 / 28 = 0.286 (2017) - Q2 - T1 Factor impacto SCIMAGO: 1.116 - Condensed Matter Physics (Q1) - Energy Engineering and Power Technology (Q1) - Fuel Technology (Q1) - Renewable Energy, Sustainability and the Environment (Q2)