doi:10.1016/j.ijhydene.2016.12.109engGarcía-Díez, E.García-Labiano, F.de Diego, L.F.Abad, A.Gayán, P.Adánez, J.Autothermal chemical looping reforming process of different fossil liquid fuelsART-2017-99007The autothermal Chemical-Looping Reforming (a-CLR) is a process where syngas is produced with two main advantages; there are captured CO2 emissions and the heat required for the syngas production is generated by the process itself. A Ni-based material is used as oxygen carrier circulating between two fluidized bed reactors: the fuel and air reactors. In this work, the auto-thermal conditions in a global H2 production process, integrated by the a-CLR process and a Water Gas Shift reactor, using different liquid fossil fuels were theoretically determined. The hydrogen production per mol of carbon in the fuel was similar for all fossil fuels, taking a value of 2.2 at the optimal operating temperature (700 °C). In addition, the possibility of working at low temperature for a maximum H2 production was experimentally demonstrated in a continuous 1 kWth a-CLR unit.2017http://zaguan.unizar.es/record/7560410.1016/j.ijhydene.2016.12.109http://zaguan.unizar.es/record/75604oai:zaguan.unizar.es:75604info:eu-repo/grantAgreement/ES/DGA/T06info:eu-repo/grantAgreement/ES/MICINN/ENE2011-26354International Journal of Hydrogen Energy 42, 19 (2017), 13633-13640by-nc-ndhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/info:eu-repo/semantics/openAccess