000075684 001__ 75684
000075684 005__ 20200117211600.0
000075684 0247_ $$2doi$$a10.1016/j.fuproc.2018.07.021
000075684 0248_ $$2sideral$$a107325
000075684 037__ $$aART-2018-107325
000075684 041__ $$aeng
000075684 100__ $$0(orcid)0000-0002-4674-3614$$aAlexandrino De Freitas, Katiuska Ferbel$$uUniversidad de Zaragoza
000075684 245__ $$aGas and soot formed in the dimethoxymethane pyrolysis. Soot characterization
000075684 260__ $$c2018
000075684 5060_ $$aAccess copy available to the general public$$fUnrestricted
000075684 5203_ $$aThe many simultaneous processes occurring within in a diesel engine make difficult a thorough understanding of the mechanisms responsible for reduction of soot and/or NOX when an oxygenated compound is added to diesel fuel. Thus, in order to explore the use of oxygenated compounds as biofuels/additives, it is interesting to study their conversion under well-controlled laboratory conditions, together with kinetic studies that help to interpret and understand the reaction schemes that occur during such processes. The aim of this work has been to contribute to the knowledge of the dimethoxymethane (DMM) pyrolysis, one of the oxygenated compounds proposed in literature as alternative fuel. In this way, the influence of pyrolysis temperature (1075–1475¿K) and inlet fuel concentration (33,333 and 50,000¿ppm DMM) on the sooting propensity of DMM, soot reactivity and its properties is analyzed. Therefore, this work includes pyrolysis experiments under different experimental conditions, focusing on the gas-phase analysis and the soot formation, together with a gas-phase model. Additionally, the interaction of soot with O2 and with NO has been studied, and since soot properties are important on the oxidation rate, selected soot samples have been characterized by different instrumental techniques (elemental analysis, physical adsorption with N2, Transmission Electron Microscopy (TEM), X-Ray Diffraction (XRD), and Raman spectroscopy).
000075684 536__ $$9info:eu-repo/grantAgreement/ES/DGA/GPT$$9info:eu-repo/grantAgreement/ES/MINECO/BES-2013-063049$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-65226
000075684 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000075684 590__ $$a4.507$$b2018
000075684 591__ $$aCHEMISTRY, APPLIED$$b11 / 71 = 0.155$$c2018$$dQ1$$eT1
000075684 591__ $$aENGINEERING, CHEMICAL$$b19 / 138 = 0.138$$c2018$$dQ1$$eT1
000075684 591__ $$aENERGY & FUELS$$b27 / 103 = 0.262$$c2018$$dQ2$$eT1
000075684 592__ $$a1.415$$b2018
000075684 593__ $$aChemical Engineering (miscellaneous)$$c2018$$dQ1
000075684 593__ $$aFuel Technology$$c2018$$dQ1
000075684 593__ $$aEnergy Engineering and Power Technology$$c2018$$dQ1
000075684 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000075684 700__ $$0(orcid)0000-0001-5426-6486$$aMillera Peralta, Ángela$$uUniversidad de Zaragoza
000075684 700__ $$0(orcid)0000-0002-5420-0943$$aBilbao Duñabeitia, Rafael$$uUniversidad de Zaragoza
000075684 700__ $$0(orcid)0000-0003-4679-5761$$aAlzueta Anía, María Ujué$$uUniversidad de Zaragoza
000075684 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000075684 7102_ $$15005$$2790$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Tecnologi. Medio Ambiente
000075684 773__ $$g179 (2018), 369-377$$pFuel process. technol.$$tFuel Processing Technology$$x0378-3820
000075684 8564_ $$s1175105$$uhttps://zaguan.unizar.es/record/75684/files/texto_completo.pdf$$yPostprint
000075684 8564_ $$s26378$$uhttps://zaguan.unizar.es/record/75684/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000075684 909CO $$ooai:zaguan.unizar.es:75684$$particulos$$pdriver
000075684 951__ $$a2020-01-17-21:11:11
000075684 980__ $$aARTICLE