000075841 001__ 75841
000075841 005__ 20200117221614.0
000075841 0247_ $$2doi$$a10.1021/acsomega.8b01696
000075841 0248_ $$2sideral$$a108381
000075841 037__ $$aART-2018-108381
000075841 041__ $$aeng
000075841 100__ $$aEcheverri, M.
000075841 245__ $$aFluorescent and Electroactive Monoalkyl BTD-Based Liquid Crystals with Tunable Self-Assembling and Electronic Properties
000075841 260__ $$c2018
000075841 5060_ $$aAccess copy available to the general public$$fUnrestricted
000075841 5203_ $$aWe report here on a series of redox active benzothiadiazole-based luminophores ffinctionalized on one edge with a phenyl-nonyl substituent, which confers these molecules a rodlike shape and a tendency to self-assemble into layered superstructures. On the other edge, the molecules are endowed with different p-substituted phenyl rings, which allows the modulation of their redox and optical properties on the basis of the electronic nature of the terminal substituents. We have found that just one lateral alkyl chain is sufficient to induce mesomorphism in these molecules, which present nematic or smectic mesophases upon therinal treatment. Single-crystal analysis allows us to get an insight into the nature of the forces responsible for different supramolecular assemblies in these derivatives, and point to a strong contribution of the terminal groups in the different arrangements observed. The interesting redox and optical properties together with their self-assembling tendencies render these new materials interesting candidates for optoelectromcs.
000075841 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2016-78557-R
000075841 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000075841 590__ $$a2.584$$b2018
000075841 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b75 / 172 = 0.436$$c2018$$dQ2$$eT2
000075841 592__ $$a0.754$$b2018
000075841 593__ $$aChemistry (miscellaneous)$$c2018$$dQ1
000075841 593__ $$aChemical Engineering (miscellaneous)$$c2018$$dQ1
000075841 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000075841 700__ $$aMartin, I.
000075841 700__ $$0(orcid)0000-0002-8932-9085$$aConcellon, A.$$uUniversidad de Zaragoza
000075841 700__ $$aRuiz, C.
000075841 700__ $$0(orcid)0000-0003-0063-9456$$aSan Anselmo, M.$$uUniversidad de Zaragoza
000075841 700__ $$aGutierrez-Puebla, E.
000075841 700__ $$0(orcid)0000-0001-9866-6633$$aSerrano, J.L.$$uUniversidad de Zaragoza
000075841 700__ $$aGomez-Lor, B.
000075841 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000075841 773__ $$g3, 9 (2018), 11857-11864$$pACS Omega$$tACS Omega$$x2470-1343
000075841 8564_ $$s520162$$uhttps://zaguan.unizar.es/record/75841/files/texto_completo.pdf$$yVersión publicada
000075841 8564_ $$s124634$$uhttps://zaguan.unizar.es/record/75841/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000075841 909CO $$ooai:zaguan.unizar.es:75841$$particulos$$pdriver
000075841 951__ $$a2020-01-17-21:49:51
000075841 980__ $$aARTICLE