000075885 001__ 75885
000075885 005__ 20200117221614.0
000075885 0247_ $$2doi$$a10.1002/admi.201800647
000075885 0248_ $$2sideral$$a108376
000075885 037__ $$aART-2018-108376
000075885 041__ $$aeng
000075885 100__ $$0(orcid)0000-0001-6627-0079$$aSanchez-Lainez, J.$$uUniversidad de Zaragoza
000075885 245__ $$aUltrapermeable Thin Film ZIF-8/Polyamide Membrane for H-2/CO2 Separation at High Temperature without Using Sweep Gas
000075885 260__ $$c2018
000075885 5060_ $$aAccess copy available to the general public$$fUnrestricted
000075885 5203_ $$aThe use of thin film composites containing metal-organic frameworks (MOFs) as filler is of widespread interest for nanofiltration issues, since their thin selective layer allows a high permeation flow. The application of this kind of membranes for gas separation should provide a better permeance in comparison with other polymeric membranes and a reduction in the amount of MOF required for their fabrication. Here, the preparation of 50-100 nm thick polyamide flat membranes containing zeolitic imidazolate framework-8 (ZIF-8) nanoparticles is shown via interfacial polymerization, containing a lower amount of MOF (0.013 g m(-2) membrane) as compared to other membranes used for gas separation. The membranes are applied for H-2/CO2 separation at high temperatures and pressures, showing a stable performance at 180 degrees C for at least seven days. Outstanding separation values are 328 GPU of H-2 and a H-2/CO2 selectivity of 18.1 at 180 degrees C and 6 bar feed without transmembrane pressure. These membranes, also measurable without sweep gas, are highly suitable for industrial application.
000075885 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/MAT2016-77290-R$$9info:eu-repo/grantAgreement/EC/FP7/608490/EU/Energy efficient MOF-based Mixed Matrix Membranes for CO2 Capture/M4CO2$$9info:eu-repo/grantAgreement/ES/DGA/T05
000075885 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000075885 590__ $$a4.713$$b2018
000075885 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b39 / 172 = 0.227$$c2018$$dQ1$$eT1
000075885 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b57 / 293 = 0.195$$c2018$$dQ1$$eT1
000075885 592__ $$a1.57$$b2018
000075885 593__ $$aMechanics of Materials$$c2018$$dQ1
000075885 593__ $$aMechanical Engineering$$c2018$$dQ1
000075885 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000075885 700__ $$0(orcid)0000-0003-2006-1495$$aPaseta, L.$$uUniversidad de Zaragoza
000075885 700__ $$0(orcid)0000-0001-7702-9619$$aNavarro, M.
000075885 700__ $$0(orcid)0000-0002-9934-1707$$aZornoza, B.$$uUniversidad de Zaragoza
000075885 700__ $$0(orcid)0000-0002-4954-1188$$aTellez, C.$$uUniversidad de Zaragoza
000075885 700__ $$0(orcid)0000-0003-1512-4500$$aCoronas, J.$$uUniversidad de Zaragoza
000075885 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000075885 773__ $$g5, 19 (2018), 1800647 [8 pp]$$pAdv. mater. interfaces$$tAdvanced materials interfaces$$x2196-7350
000075885 8564_ $$s494471$$uhttps://zaguan.unizar.es/record/75885/files/texto_completo.pdf$$yVersión publicada
000075885 8564_ $$s121883$$uhttps://zaguan.unizar.es/record/75885/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000075885 909CO $$ooai:zaguan.unizar.es:75885$$particulos$$pdriver
000075885 951__ $$a2020-01-17-21:49:49
000075885 980__ $$aARTICLE