000077236 001__ 77236
000077236 005__ 20200117221614.0
000077236 0247_ $$2doi$$a10.1021/acs.energyfuels.8b00920
000077236 0248_ $$2sideral$$a108337
000077236 037__ $$aART-2018-108337
000077236 041__ $$aeng
000077236 100__ $$0(orcid)0000-0002-7767-3057$$aMarrodán, Lorena$$uUniversidad de Zaragoza
000077236 245__ $$aEthanol as a Fuel Additive: High-Pressure Oxidation of Its Mixtures with Acetylene
000077236 260__ $$c2018
000077236 5060_ $$aAccess copy available to the general public$$fUnrestricted
000077236 5203_ $$aAn experimental and modeling study of the oxidation of acetylene-ethanol mixtures under high-pressure conditions (10-40 bar) has been carried out in the 575-1075 K temperature range in a plug-flow reactor. The influence on the oxidation process of the oxygen inlet concentration (determined by the air excess ratio, λ) and the amount of ethanol (0-200 ppm) present in the reactant mixture has also been evaluated. In general, the predictions obtained with the proposed model are in satisfactory agreement with the experimental data. For a given pressure, the onset temperature for acetylene conversion is almost the same independent of the oxygen or ethanol concentration in the reactant mixture but is shifted to lower temperatures when the pressure is increased. Under the conditions of this study, the ethanol presence does not modify the main reaction routes for acetylene conversion, with its main effect being the modification of the radical pool composition.
000077236 536__ $$9info:eu-repo/grantAgreement/ES/DGA/GPT$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-65226
000077236 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000077236 590__ $$a3.021$$b2018
000077236 591__ $$aENGINEERING, CHEMICAL$$b46 / 138 = 0.333$$c2018$$dQ2$$eT2
000077236 591__ $$aENERGY & FUELS$$b52 / 103 = 0.505$$c2018$$dQ3$$eT2
000077236 592__ $$a1.035$$b2018
000077236 593__ $$aChemical Engineering (miscellaneous)$$c2018$$dQ1
000077236 593__ $$aFuel Technology$$c2018$$dQ1
000077236 593__ $$aEnergy Engineering and Power Technology$$c2018$$dQ1
000077236 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000077236 700__ $$aFuster, Miguel
000077236 700__ $$0(orcid)0000-0001-5426-6486$$aMillera, Ángela$$uUniversidad de Zaragoza
000077236 700__ $$0(orcid)0000-0002-5420-0943$$aBilbao, Rafael$$uUniversidad de Zaragoza
000077236 700__ $$0(orcid)0000-0003-4679-5761$$aAlzueta, María U.$$uUniversidad de Zaragoza
000077236 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000077236 7102_ $$15005$$2790$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Tecnologi. Medio Ambiente
000077236 773__ $$g32, 10 (2018), 10078-10087$$pEnergy fuels$$tEnergy and Fuels$$x0887-0624
000077236 8564_ $$s311415$$uhttps://zaguan.unizar.es/record/77236/files/texto_completo.pdf$$yPostprint
000077236 8564_ $$s59989$$uhttps://zaguan.unizar.es/record/77236/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000077236 909CO $$ooai:zaguan.unizar.es:77236$$particulos$$pdriver
000077236 951__ $$a2020-01-17-21:50:14
000077236 980__ $$aARTICLE