77243 20210121114447.0 doi 10.1016/j.ijhydene.2015.01.078 sideral 91549 ART-2015-91549 eng Lemus, J. UV polymerization of room temperature ionic liquids for high temperature PEMs: Study of ionic moieties and crosslinking effects 2015 Access copy available to the general public Unrestricted The conductivity performance of commercial available room-temperature ionic liquids (RTILs) has been evaluated from room conditions up to 200oC as a function of relative humidity for their potential application in high temperature PEMs. In particular, ammonium and imidazolium based ionic liquids with different counterions and substituents have been investigated. On the basis of conductivity performance, the best RTILs have been selected for the preparation of all solid state ion conductive films by bulk photo-assisted radical polymerization. The goodness of the UV photopolymerization of the respective monomeric ionic liquids (MILs) with vinyl functionality as a function of divynilbenzene cross-linker content has been evaluated by TGA and FTIR analyses. Poly-ionic liquid (PIL) films have been successfully accomplished for polymerized H-3-vinylimidazolium bis(trifluoromethanesulfonyl)imide upon exposure to 365 nm UV lamp with an intensity of 2.4 mW/cm2 for 15 min. Conductivity values above 1.1 S∙cm-1 at 200oC have been registered for pure poly[1-(3H-imidazolium)ethylene] bis(trifluoromethanesulfonyl)imide. info:eu-repo/grantAgreement/EC/FP7/209481/EU/NANOSTRUCTURED ELECTROLYTE MEMBRANES BASED ON POLYMER-IONIC LIQUIDS-ZEOLITE COMPOSITES FOR HIGH TEMPERATURE PEM FUEL CELL/ZEOCELL info:eu-repo/semantics/openAccess by-nc-nd http://creativecommons.org/licenses/by-nc-nd/3.0/es/ 3.205 2015 CHEMISTRY, PHYSICAL 47 / 144 = 0.326 2015 Q2 T1 ENERGY & FUELS 28 / 88 = 0.318 2015 Q2 T1 ELECTROCHEMISTRY 8 / 27 = 0.296 2015 Q2 T1 1.27 2015 Condensed Matter Physics 2015 Q1 Renewable Energy, Sustainability and the Environment 2015 Q1 Fuel Technology 2015 Q1 Energy Engineering and Power Technology 2015 Q1 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion (orcid)0000-0001-5973-4330 Eguizábal, A. (orcid)0000-0001-9897-6527 Pina, M. P. Universidad de Zaragoza 5005 555 Universidad de Zaragoza Dpto. Ing.Quím.Tecnol.Med.Amb. Área Ingeniería Química 40, 15 (2015), 5416-5424 Int. j. hydrogen energy International Journal of Hydrogen Energy 0360-3199 1127328 http://zaguan.unizar.es/record/77243/files/texto_completo.pdf Postprint 67416 http://zaguan.unizar.es/record/77243/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:77243 articulos driver 2021-01-21-10:44:02 ARTICLE