000078184 001__ 78184
000078184 005__ 20200716101524.0
000078184 0247_ $$2doi$$a10.1039/c8cc07185c
000078184 0248_ $$2sideral$$a110673
000078184 037__ $$aART-2019-110673
000078184 041__ $$aeng
000078184 100__ $$aLiu, L.
000078184 245__ $$aGeneration of gold nanoclusters encapsulated in an MCM-22 zeolite for the aerobic oxidation of cyclohexane
000078184 260__ $$c2019
000078184 5060_ $$aAccess copy available to the general public$$fUnrestricted
000078184 5203_ $$aIn this work, we will report the generation of Au clusters in a purely siliceous MCM-22 zeolite. The catalytic properties of these Au clusters have been tested for the selective oxidation of cyclohexane to cyclohexanol and cyclohexanone (KA-oil). The Au clusters encapsulated in the MCM-22 zeolite are highly active and selective for the oxidation of cyclohexane to KA-oil, which is superior to Au nanoparticles on the same support. These results suggest that Au clusters are highly active for the activation of oxygen to produce radical species.
000078184 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/MAT2016-79776-P
000078184 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/
000078184 590__ $$a5.996$$b2019
000078184 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b34 / 177 = 0.192$$c2019$$dQ1$$eT1
000078184 592__ $$a1.992$$b2019
000078184 593__ $$aCatalysis$$c2019$$dQ1
000078184 593__ $$aCeramics and Composites$$c2019$$dQ1
000078184 593__ $$aChemistry (miscellaneous)$$c2019$$dQ1
000078184 593__ $$aSurfaces, Coatings and Films$$c2019$$dQ1
000078184 593__ $$aMaterials Chemistry$$c2019$$dQ1
000078184 593__ $$aMetals and Alloys$$c2019$$dQ1
000078184 593__ $$aElectronic, Optical and Magnetic Materials$$c2019$$dQ1
000078184 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000078184 700__ $$0(orcid)0000-0002-2071-9093$$aArenal, R.$$uUniversidad de Zaragoza
000078184 700__ $$aMeira, D.M.
000078184 700__ $$aCorma, A.
000078184 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDpto. Física Materia Condensa.$$cÁrea Física Materia Condensada
000078184 773__ $$g55, 11 (2019), 1607-1610$$pChem. commun.$$tCHEMICAL COMMUNICATIONS$$x1359-7345
000078184 8564_ $$s1482945$$uhttps://zaguan.unizar.es/record/78184/files/texto_completo.pdf$$yVersión publicada
000078184 8564_ $$s123477$$uhttps://zaguan.unizar.es/record/78184/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000078184 909CO $$ooai:zaguan.unizar.es:78184$$particulos$$pdriver
000078184 951__ $$a2020-07-16-09:28:36
000078184 980__ $$aARTICLE