Pentacoordinated Rhodium(I) Complexes Supported by Coumarin-Functionalized N-Heterocyclic Carbene Ligands

Karatas, M.O. ; Di Giuseppe, A. (Universidad de Zaragoza) ; Passarelli, V. ; Allcl, B. ; Pérez-Torrente, J.J. (Universidad de Zaragoza) ; Oro, L.A. (Universidad de Zaragoza) ; Özdemir, I. ; Castarlenas, R. (Universidad de Zaragoza)

Resumen: New coumarin-Tethered benzimidazolium (BzICouRHCl) and imidazolium (ICouRHCl) salts have been prepared as precursors for coumarin-NHC rhodium(I) complexes RhCl(NHC)(cod). Trigonal bypiramidal pentacoordinated bis-coumarin-NHC rhodium(I) species, RhCl(NHC)2, can be obtained by heating rhodium-cod derivatives in the presence of coumarin-Azolium salts and a base. These unusual species are stabilized by coordination of the unsaturated bond of both coumarin moieties by the same enantioface. The allyl substituent on doubly functionalized NHC competes for coordination with coumarin wingtips. DFT calculations upon coordination of the olefin moieties support the experimental results.

Idioma: Inglés

DOI: 10.1021/acs.organomet.7b00750

Año: 2018

Publicado en: Organometallics 37, 2 (2018), 191-202
ISSN: 0276-7333

Factor impacto JCR: 4.1 (2018)

Categ. JCR: CHEMISTRY, ORGANIC rank: 11 / 57 = 0.193 (2018) - Q1 - T1
Categ. JCR: CHEMISTRY, INORGANIC & NUCLEAR rank: 5 / 45 = 0.111 (2018) - Q1 - T1

Factor impacto SCIMAGO: 1.473 - Inorganic Chemistry (Q1) - Physical and Theoretical Chemistry (Q1) - Organic Chemistry (Q1)

Financiación: info:eu-repo/grantAgreement/ES/CSIC/201680I011
Financiación: info:eu-repo/grantAgreement/ES/DGA/E07
Financiación: info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2013-42532-P
Financiación: info:eu-repo/grantAgreement/ES/MINECO/IJCI-2015-27029

Tipo y forma: Artículo (PostPrint)

Área (Departamento): Área Química Inorgánica (Dpto. Química Inorgánica)