000078288 001__ 78288 000078288 005__ 20191127155500.0 000078288 0247_ $$2doi$$a10.1002/chem.201705509 000078288 0248_ $$2sideral$$a104591 000078288 037__ $$aART-2018-104591 000078288 041__ $$aeng 000078288 100__ $$0(orcid)0000-0002-2492-625X$$aBaya, M.$$uUniversidad de Zaragoza 000078288 245__ $$aGold(II) Trihalide Complexes from Organogold(III) Precursors 000078288 260__ $$c2018 000078288 5060_ $$aAccess copy available to the general public$$fUnrestricted 000078288 5203_ $$aThe mononuclear gold(II) halide complexes [AuCl3]- and [AuBr3]- are formed in the gas phase by collision-induced homolytic splitting of the only Au-C bond in the monoalkylgold(III) precursors [CF3AuX3]-. The geometries of the whole series of [AuX3]- complexes (X=F, Cl, Br, I) have been calculated by DFT methods. It has also been found that the neutral AuX2 molecules behave as unsaturated species, showing significant affinity for an additional X- ligand. Moreover, in the open-shell [AuX3]- anions, homolytic splitting of one of the Au-X bonds and formation of the lower-valent [AuX2]- anions is favored over non-reducing halide dissociation. They should therefore be prone to disproportionation. 000078288 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E21$$9info:eu-repo/grantAgreement/ES/MEC/FPU15-03940$$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2015-67461-P 000078288 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/ 000078288 590__ $$a5.16$$b2018 000078288 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b36 / 172 = 0.209$$c2018$$dQ1$$eT1 000078288 592__ $$a1.842$$b2018 000078288 593__ $$aCatalysis$$c2018$$dQ1 000078288 593__ $$aOrganic Chemistry$$c2018$$dQ1 000078288 593__ $$aChemistry (miscellaneous)$$c2018$$dQ1 000078288 655_4 $$ainfo:eu-repo/semantics/conferenceObject$$vinfo:eu-repo/semantics/acceptedVersion 000078288 700__ $$0(orcid)0000-0003-2260-676X$$aPérez-Bitrián, A.$$uUniversidad de Zaragoza 000078288 700__ $$0(orcid)0000-0002-7920-4000$$aMartínez-Salvador, S. 000078288 700__ $$0(orcid)0000-0002-4808-574X$$aMartín, A.$$uUniversidad de Zaragoza 000078288 700__ $$0(orcid)0000-0003-0341-7699$$aCasas, J.M.$$uUniversidad de Zaragoza 000078288 700__ $$0(orcid)0000-0001-9045-5102$$aMenjón, B. 000078288 700__ $$0(orcid)0000-0003-3514-2570$$aOrduna, J.$$uUniversidad de Zaragoza 000078288 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica 000078288 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica 000078288 773__ $$g24, 7 (2018), 1514-1517$$pChemistry (Weinh.)$$tChemistry - A European Journal$$x0947-6539 000078288 8564_ $$s325764$$uhttps://zaguan.unizar.es/record/78288/files/texto_completo.pdf$$yPostprint 000078288 8564_ $$s21180$$uhttps://zaguan.unizar.es/record/78288/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint 000078288 909CO $$ooai:zaguan.unizar.es:78288$$particulos$$pdriver 000078288 951__ $$a2019-11-27-15:49:44 000078288 980__ $$aARTICLE