000078289 001__ 78289
000078289 005__ 20191212100659.0
000078289 0247_ $$2doi$$a10.1021/jacs.7b12731
000078289 0248_ $$2sideral$$a104617
000078289 037__ $$aART-2018-104617
000078289 041__ $$aeng
000078289 100__ $$0(orcid)0000-0002-2343-0156$$aCarmona, M.
000078289 245__ $$aMetal as Source of Chirality in Octahedral Complexes with Tripodal Tetradentate Ligands
000078289 260__ $$c2018
000078289 5060_ $$aAccess copy available to the general public$$fUnrestricted
000078289 5203_ $$aThe challenging control of the absolute configuration of chiral-at-metal complexes is efficiently achieved using the tripodal tetradentate ligand L. The optical resolution of rac-[RhCl2(¿4C, N, N', P-L)] mediated by (S)-a-phenylglycine provides access to enantiopure complexes of general formula [Rh(¿4C, N, N', P-L)A(Solv)][SbF6]n that enantioselectively catalyze the Diels-Alder reaction between methacrolein and HCp with enantiomeric ratio of up to >99/1. The nature of the active species, the origin of the enantioselectivity and mechanistic details are disclosed by means of NMR spectroscopy and DFT studies.
000078289 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E63$$9info:eu-repo/grantAgreement/ES/DGA/FSE$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-66079-P$$9info:eu-repo/grantAgreement/ES/MINECO/RYC-2013-13800
000078289 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000078289 590__ $$a14.695$$b2018
000078289 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b12 / 172 = 0.07$$c2018$$dQ1$$eT1
000078289 592__ $$a7.468$$b2018
000078289 593__ $$aBiochemistry$$c2018$$dQ1
000078289 593__ $$aColloid and Surface Chemistry$$c2018$$dQ1
000078289 593__ $$aChemistry (miscellaneous)$$c2018$$dQ1
000078289 593__ $$aCatalysis$$c2018$$dQ1
000078289 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000078289 700__ $$0(orcid)0000-0002-8845-0174$$aRodríguez, R.$$uUniversidad de Zaragoza
000078289 700__ $$0(orcid)0000-0002-1735-6439$$aPassarelli, V.
000078289 700__ $$0(orcid)0000-0001-8054-2237$$aLahoz, F.J.$$uUniversidad de Zaragoza
000078289 700__ $$0(orcid)0000-0002-7063-1292$$aGarcía-Orduna, P.$$uUniversidad de Zaragoza
000078289 700__ $$0(orcid)0000-0003-4196-5856$$aCarmona, D.
000078289 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000078289 773__ $$g140, 3 (2018), 912-915$$pJ. Am. Chem. Soc.$$tJOURNAL OF THE AMERICAN CHEMICAL SOCIETY$$x0002-7863
000078289 8564_ $$s250101$$uhttps://zaguan.unizar.es/record/78289/files/texto_completo.pdf$$yPostprint
000078289 8564_ $$s71605$$uhttps://zaguan.unizar.es/record/78289/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000078289 909CO $$ooai:zaguan.unizar.es:78289$$particulos$$pdriver
000078289 951__ $$a2019-12-12-10:03:43
000078289 980__ $$aARTICLE