000078291 001__ 78291
000078291 005__ 20200103141020.0
000078291 0247_ $$2doi$$a10.1039/c7dt04293k
000078291 0248_ $$2sideral$$a104650
000078291 037__ $$aART-2018-104650
000078291 041__ $$aeng
000078291 100__ $$aCostes, J.P.
000078291 245__ $$aNiII-LnIII complexes with: O -vanillin as the main ligand: Syntheses, structures, magnetic and magnetocaloric properties
000078291 260__ $$c2018
000078291 5060_ $$aAccess copy available to the general public$$fUnrestricted
000078291 5203_ $$aortho-Vanillin in the presence of nickel and lanthanide ions yields three types of heteronuclear NiII-GdIII complexes, ranging from dinuclear to tetranuclear defect dicubane complexes, as demonstrated by their structural determinations. These complexes are dependent on the solvents used during the reaction processes and on the retained lanthanide ions, as characterized by an increase in their Lewis acid character on moving from lighter to heavier lanthanide ions. Intramolecular ferromagnetic NiII-GdIII interactions are present in the heterodinuclear NiII-GdIII entities, whereas ferromagnetic NiII-NiII and NiII-GdIII interactions dominate above 2 K in the tetranuclear NiII2-GdIII2 compounds, devoid of any GdIII-GdIII interaction. The effect of a magnetic field on the magnetic entropy and adiabatic temperature changes is maximum near the liquid-helium boiling temperature, mainly determined by the relative weakness of the magnetic interactions.
000078291 536__ $$9info:eu-repo/grantAgreement/EUR/FP6/NMP-MAGMANET-515767$$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/MAT2015-68204-R
000078291 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000078291 590__ $$a4.052$$b2018
000078291 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b7 / 45 = 0.156$$c2018$$dQ1$$eT1
000078291 592__ $$a1.12$$b2018
000078291 593__ $$aInorganic Chemistry$$c2018$$dQ1
000078291 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000078291 700__ $$aDahan, F.
000078291 700__ $$aVendier, L.
000078291 700__ $$aShova, S.
000078291 700__ $$0(orcid)0000-0002-4078-6808$$aLorusso, G.
000078291 700__ $$0(orcid)0000-0002-8028-9064$$aEvangelisti, M.$$uUniversidad de Zaragoza
000078291 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDpto. Física Materia Condensa.$$cÁrea Física Materia Condensada
000078291 773__ $$g47, 4 (2018), 1106-1116$$pDalton Trans.$$tDalton Transactions$$x1477-9226
000078291 8564_ $$s753821$$uhttps://zaguan.unizar.es/record/78291/files/texto_completo.pdf$$yPostprint
000078291 8564_ $$s51211$$uhttps://zaguan.unizar.es/record/78291/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000078291 909CO $$ooai:zaguan.unizar.es:78291$$particulos$$pdriver
000078291 951__ $$a2020-01-03-14:01:04
000078291 980__ $$aARTICLE