000078344 001__ 78344
000078344 005__ 20200117213749.0
000078344 0247_ $$2doi$$a10.1021/acs.iecr.7b05103
000078344 0248_ $$2sideral$$a105335
000078344 037__ $$aART-2018-105335
000078344 041__ $$aeng
000078344 100__ $$0(orcid)0000-0001-9791-1326$$aDíez-Martín, L.
000078344 245__ $$aDevelopment of Suitable CuO-Based Materials Supported on Al2O3, MgAl2O4, and ZrO2 for Ca/Cu H2 Production Process
000078344 260__ $$c2018
000078344 5060_ $$aAccess copy available to the general public$$fUnrestricted
000078344 5203_ $$aFunctional materials for the sorption enhanced reforming process for H2 production coupled to a Cu/CuO chemical loop have been synthesized. The performance of CuO-based materials supported on Al2O3, MgAl2O4, and ZrO2 and synthesized by different routes has been analyzed. Highly stable materials supported on Al2O3 or MgAl2O4 synthesized by coprecipitation and mechanical mixing with sufficient Cu loads (around 65% wt) have been successfully developed. However, it has been found that coprecipitation under these conditions is not a suitable route for ZrO2. Spray-drying and deposition precipitation did not provide the best chemical features to the materials. As the Ca/Cu process is operated in fixed bed reactors, the best candidates were pelletized and their stability was again assessed. Pellets with high chemical and mechanical stability, high oxygen transport capacity, and good mechanical properties have been finally obtained by coprecipitation. The good homogeneity that provides this route would allow an easy scaling up.
000078344 536__ $$9info:eu-repo/grantAgreement/ES/MICINN/ENE-2012-37936-CO2-01$$9info:eu-repo/grantAgreement/ES/MICINN/BES-2013-064616$$9info:eu-repo/grantAgreement/EC/FP7/608512/EU/ASCENT - Advanced Solid Cycles with Efficient Novel Technologies/ASCENT
000078344 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000078344 590__ $$a3.375$$b2018
000078344 591__ $$aENGINEERING, CHEMICAL$$b33 / 138 = 0.239$$c2018$$dQ1$$eT1
000078344 592__ $$a0.907$$b2018
000078344 593__ $$aChemical Engineering (miscellaneous)$$c2018$$dQ1
000078344 593__ $$aIndustrial and Manufacturing Engineering$$c2018$$dQ1
000078344 593__ $$aChemistry (miscellaneous)$$c2018$$dQ1
000078344 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000078344 700__ $$0(orcid)0000-0002-4242-5846$$aGrasa, G.
000078344 700__ $$0(orcid)0000-0002-0299-506X$$aMurillo, R.
000078344 700__ $$aScullard, A.
000078344 700__ $$aWilliams, G.
000078344 773__ $$g57, 8 (2018), 2890-2904$$pInd. eng. chem. res.$$tINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH$$x0888-5885
000078344 8564_ $$s974360$$uhttps://zaguan.unizar.es/record/78344/files/texto_completo.pdf$$yPostprint
000078344 8564_ $$s75006$$uhttps://zaguan.unizar.es/record/78344/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000078344 909CO $$ooai:zaguan.unizar.es:78344$$particulos$$pdriver
000078344 951__ $$a2020-01-17-21:31:26
000078344 980__ $$aARTICLE