000078354 001__ 78354
000078354 005__ 20200117221627.0
000078354 0247_ $$2doi$$a10.1002/cctc.201701488
000078354 0248_ $$2sideral$$a105469
000078354 037__ $$aART-2018-105469
000078354 041__ $$aeng
000078354 100__ $$0(orcid)0000-0003-4695-6967$$aJulián, A.
000078354 245__ $$aReactivity of Ir–NSiN Complexes: Ir-Catalyzed Dehydrogenative Silylation of Carboxylic Acids
000078354 260__ $$c2018
000078354 5060_ $$aAccess copy available to the general public$$fUnrestricted
000078354 5203_ $$aThis work describes the results from the studies on the potential of [Ir(µ-Cl)(cod)]2 (cod=1,5-cyclooctadiene) as metallic precursor for the preparation of Ir(NSiN) complexes (NSiN=fac-bis-(pyridine-2-yloxy)methylsilyl). The reaction of [Ir(µ-Cl)(cod)]2 with bis-(pyridine-2-yloxy)methylsilane enabled the synthesis of [Ir(H)(Cl)(NSiN)(¿2-cod)] with an uncommon ¿2-coordination mode for the cod ligand. The application of Ir–NSiN species as catalysts precursors for the dehydrogenative silylation of carboxylic acids was also explored. The outcomes from these catalytic studies revealed a clear influence of the ancillary ligand on the catalytic activity of Ir–NSiN species. Thus, whereas [Ir(H)(CF3SO3)(NSiN)(coe)] shows poor catalytic activity, the related complex [Ir(H)(CF3CO2)(NSiN)(coe)] with a trifluoroacetate ligand was demonstrated to be a highly active catalyst precursor.
000078354 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/E07$$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2013-42532-P$$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2015-67366-P$$9info:eu-repo/grantAgreement/ES/MINECO-FSE/PTA contract
000078354 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000078354 590__ $$a4.495$$b2018
000078354 591__ $$aCHEMISTRY, PHYSICAL$$b43 / 148 = 0.291$$c2018$$dQ2$$eT1
000078354 592__ $$a1.472$$b2018
000078354 593__ $$aCatalysis$$c2018$$dQ1
000078354 593__ $$aPhysical and Theoretical Chemistry$$c2018$$dQ1
000078354 593__ $$aOrganic Chemistry$$c2018$$dQ1
000078354 593__ $$aInorganic Chemistry$$c2018$$dQ1
000078354 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000078354 700__ $$0(orcid)0000-0001-8727-3404$$aGarcés, K.
000078354 700__ $$aLalrempuia, R.
000078354 700__ $$aJaseer, E.A.
000078354 700__ $$0(orcid)0000-0002-7063-1292$$aGarcía-Orduña, P.$$uUniversidad de Zaragoza
000078354 700__ $$0(orcid)0000-0002-0497-1969$$aFernández-Alvarez, F.J.$$uUniversidad de Zaragoza
000078354 700__ $$0(orcid)0000-0001-8054-2237$$aLahoz, F.J.$$uUniversidad de Zaragoza
000078354 700__ $$0(orcid)0000-0001-7154-7239$$aOro, L.A.$$uUniversidad de Zaragoza
000078354 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000078354 773__ $$g10, 5 (2018), 1027-1034$$pChemCatChem$$tChemCatChem$$x1867-3880
000078354 8564_ $$s619549$$uhttps://zaguan.unizar.es/record/78354/files/texto_completo.pdf$$yPostprint
000078354 8564_ $$s18951$$uhttps://zaguan.unizar.es/record/78354/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000078354 909CO $$ooai:zaguan.unizar.es:78354$$particulos$$pdriver
000078354 951__ $$a2020-01-17-21:57:42
000078354 980__ $$aARTICLE